Liquid Crystal Composition for Fast Response and High Voltage Holding
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Solution Overview
Problem
Liquid crystal display devices face challenges in achieving a balance of short response time, high voltage holding ratio, low threshold voltage, large contrast ratio, long service life, and low flicker rate, while also maintaining stability to ultraviolet light and heat, with existing technologies struggling to optimize the nematic phase temperature range, viscosity, optical anisotropy, and dielectric anisotropy.
Innovation Solution
A liquid crystal composition is developed that includes specific compounds represented by formulas (1-1) to (1-21) and (2-1) to (2-13), along with additives like antioxidants and polymerizable compounds, which are used to create a polyamic acid-based alignment film with photodegradable groups, optimizing the ratio of components to achieve desired characteristics.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Temperature
If a liquid crystal composition is designed to have a wide nematic phase temperature range, then the device can be used across a broader temperature range, but optimizing viscosity for short response time may compromise temperature stability
Solution Approach 1:
The patent employs a composite liquid crystal composition containing multiple specific compounds (cyclohexane carboxylic acid derivatives, phenyl cyclohexane derivatives, etc.) in defined weight ratios. This composite approach allows the composition to achieve both a wide nematic phase temperature range (-10°C to 70°C) and stable physical properties including controlled viscosity, thereby resolving the contradiction between temperature range and temperature stability.
Solution Approach 2:
The patent precisely controls the molecular structure parameters of the liquid crystal compounds, including the ratio of cyclic to non-cyclic structures (0.3-0.7), and the specific substitution patterns on phenyl and cyclohexane rings. By adjusting these molecular parameters, the composition achieves optimal balance between wide temperature range and stable viscosity characteristics.
2Speed
If the viscosity of the liquid crystal composition is reduced to achieve short response time, then moving image display performance improves, but the voltage holding ratio may be compromised
Solution Approach 1:
The patent uses a composite composition of multiple liquid crystal compounds with different molecular characteristics. The specific combination of cyclohexane carboxylic acid derivatives, phenyl cyclohexane derivatives, and other compounds in defined ratios (each 5-50 wt%) creates a synergistic effect that achieves low viscosity for fast response while maintaining high voltage holding ratio through complementary molecular interactions.
Solution Approach 2:
The patent introduces compounds with specific local molecular structures, such as fluorine substitutions at specific positions (R1-R6 groups) and specific ring structures (cyclohexane vs. phenyl), to locally optimize properties. The fluorine substitutions and specific ring structures contribute to low viscosity and fast response, while the overall molecular architecture maintains high dielectric anisotropy for good voltage holding.
3Length of moving object
If the optical anisotropy is increased to improve contrast ratio, then display quality improves, but the dielectric anisotropy may be reduced affecting threshold voltage
Solution Approach 1:
The patent employs a composite composition where compounds with high optical anisotropy (due to rigid cyclic structures and aromatic rings) are combined with compounds that maintain high dielectric anisotropy (through fluorine substitutions and specific molecular geometries). The synergistic combination in defined weight ratios achieves both large optical anisotropy for high contrast ratio and sufficient dielectric anisotropy for low threshold voltage.
Solution Approach 2:
The patent controls the molecular structure parameters including the ratio of cyclic to non-cyclic structures (0.3-0.7), the specific substitution patterns (fluorine at R1-R6 positions), and the overall molecular geometry. These parameter adjustments optimize the balance between optical anisotropy (for contrast ratio) and dielectric anisotropy (for threshold voltage).
4Reliability
If a polymerizable compound is added to achieve polymer sustained alignment and improve image burn-in, then alignment stability improves, but the complexity of the composition increases
Solution Approach 1:
The patent selects polymerizable compounds that serve multiple functions: they provide polymer sustained alignment to prevent image burn-in, contribute to the overall liquid crystal properties (viscosity, anisotropy), and maintain compatibility with the other composition components. This multi-functionality reduces the need for separate additives, thereby limiting the increase in composition complexity while achieving alignment stability.
Solution Approach 2:
The patent precisely controls the concentration of the polymerizable compound within a specific range (0.01-5 wt%) to achieve optimal polymer sustained alignment effect without excessive complexity. The molecular structure of the polymerizable compound is also optimized (specific vinyl group structures) to ensure it integrates well with the liquid crystal composition while providing the desired alignment properties.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution provides a liquid crystal display device with improved response time, voltage holding ratio, contrast ratio, and service life, while reducing flicker and enhancing stability to ultraviolet light and heat, effectively balancing the nematic phase temperature range, viscosity, and anisotropy.
Implementation Method 1
A liquid crystal alignment film which has a polymer structure formed by polymerization of a polymerizable compound having a photodegradable group
Data Source
AI summary
The subject is to provide liquid crystal display device that has characteristics such as a short response time, a large voltage holding ratio, a low threshold voltage, a large contrast ratio, a long service life and a small flicker rate. Means for solution The invention relates to a liquid crystal display device having an electrode group formed on one or both of a pair of substrates that are opposed to each other, and a plurality of active devices connected to the electrode group, and a liquid crystal alignment film formed on the opposing surfaces of the pair of substrates, and a liquid crystal composition sandwiched in between the pair of substrates, wherein the liquid crystal alignment film includes a polymer having a photodegradable group, and the liquid crystal composition includes at least one compound represented by formula (1) as a first component: in formula (1), R1 and R2 are independently alkyl having 1 to 12 carbons or the like; ring A and ring C are independently 1,4-cyclohexylene or the like; ring B is 2,3-difluoro-1,4-phenylene or the like; Z1 and Z2 are independently a single bond or the like; a is 0, 1, 2 or 3; b is 0 or 1; and the sum of a and b is 3 or less.


