Liquid Crystal Medium Stabilization for ECB Displays

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing liquid crystal displays using the ECB effect with dielectrically negative liquid crystals face challenges such as high operating voltages, low specific resistance, and instability under UV and temperature stress, leading to issues like flicker and insufficient transmission, especially in mobile applications where continuous power supply is not guaranteed.

Innovation Solution

A liquid crystal medium comprising a mixture of compounds with specific chemical structures, including those of formulas I, II, III-O, and III-3, which provide a broad nematic phase range, high negative dielectric anisotropy, low rotational viscosity, and stability against UV and temperature exposure, enabling low threshold voltage, short switching times, and high voltage holding ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If liquid crystal media with high negative dielectric anisotropy are used to achieve low threshold voltage, then the operating voltage is reduced, but the stability under UV and temperature stress deteriorates

Engineering Contradiction:
Improvethreshold voltageVSAvoidstability under UV and temperature stress
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent employs a composite liquid crystal mixture containing multiple compounds with specific molecular structures (cyclic carbonate groups, cyano groups, and specific alkyl chains) that work synergistically to achieve both low threshold voltage through high negative dielectric anisotropy and high stability through UV absorbers and temperature-resistant structures

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific physical parameters of the liquid crystal compounds including molecular weight, chain length, and functional group composition to balance dielectric anisotropy (for low voltage) with thermal stability and UV resistance, achieving a optimal combination of electrical and stability properties

Inventive Principle:
Principle #35Parameter changes

2Speed

If liquid crystal media are used to achieve short switching times, then the response speed is improved, but the voltage holding capacity deteriorates

Engineering Contradiction:
Improveswitching timeVSAvoidvoltage holding capacity
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent carefully controls the rotational viscosity parameter and dielectric anisotropy parameter of the liquid crystal mixture to achieve short switching times while maintaining adequate voltage holding capacity through optimized molecular structure and composition

Inventive Principle:
Principle #35Parameter changes

3Speed

If liquid crystal media with low rotational viscosity are used to achieve short switching times, then the switching speed is improved, but the stability against UV irradiation deteriorates

Engineering Contradiction:
Improveswitching timeVSAvoidstability against UV irradiation
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent creates a composite liquid crystal system that combines low-viscosity compounds for fast switching with UV-stabilized compounds containing cyclic carbonate groups and aromatic structures that provide UV absorption and photostability

Inventive Principle:
Principle #40Composite materials

4Reliability

If liquid crystal media are used to achieve high specific resistance, then the flicker is reduced, but the manufacturing complexity increases

Engineering Contradiction:
Improvespecific resistanceVSAvoidmixture composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent achieves high specific resistance by optimizing the ionic content and molecular structure parameters of the liquid crystal compounds, using high-purity synthetic routes and controlled purification processes to minimize impurities while maintaining manageable mixture composition

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid crystal medium achieves low threshold voltage, short switching times, and high stability, ensuring reliable operation in extreme temperatures and reducing flicker and transmission issues, making it suitable for mobile and other demanding applications.

Implementation Method 1

The principle of electrically controlled birefringence, the ECB effect or DAP effect (Deformation a more erect P hasen) was first described in 1971

Methodology Applied
Scientific EffectElectrically controlled birefringence: Birefringence

Implementation Method 2

high values for the dielectric anisotropy Δε ≤ -0.5 in order to be based on highly informative display elements to be used on the ECB effect

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Data Source

PatentEP3327103B1Liquid crystal medium, method for the stabilisation thereof and liquid crystal display
Publication Date: 2020.10.14 MERCK PATENT GMBH
  • EP3327103B1 patent drawing
  • EP3327103B1 patent drawing
  • EP3327103B1 patent drawing

AI summary

The invention relates to compounds of formula I, as well as a liquid crystalline medium, preferably with a nematic phase and a negative dielectric anisotropy, which contains a) one or more compounds of formula I and b) one or more compounds of formula III-O, wherein the parameters have the respective meanings specified in claim 1, its use in an electro-optical display, particularly in an active matrix display based on the VA, ECB, PALC, FFS or IPS effect, such displays which contain such a liquid crystalline medium, as well as the use of the compounds of formula I for stabilizing a liquid crystalline medium which contains one or more compounds of formula III-O.