LC Medium with Formula I Compounds for Fast Response

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Solution Overview

Problem

Existing liquid crystal (LC) media for displays, particularly in IPS, FFS, TN, and STN modes, face issues with long addressing times, high operating voltages, inadequate resistivity, and limited shelf life, which are critical for public and automotive displays requiring high reliability and wide operating ranges.

Innovation Solution

An LC medium with positive dielectric anisotropy, containing specific compounds of formula I, is developed, which improves properties such as dielectric anisotropy, rotational viscosity, and clearing temperature, enabling faster response times and lower operating voltages, suitable for active matrix displays like TFTs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional LC media are used in IPS, FFS, TN, and STN displays, then the displays can operate with standard components, but the addressing times become excessively long and response speeds decrease

Engineering Contradiction:
Improveaddressing timeVSAvoiddisplay performance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition of the LC medium through specific compounds of formula I with controlled alkyl chain lengths (R1 and R2 with 1-6 C atoms). This changes the rotational viscosity and dielectric anisotropy parameters, achieving faster addressing times while maintaining stable operation across temperature ranges.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by formulating an LC medium that combines compounds of formula I with other LC compounds in specific concentrations (≤10% of formula I compounds). This composite approach achieves synergistic effects, improving both response speed and operational reliability through the combined properties of multiple compounds.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If LC media with higher dielectric anisotropy are used to reduce operating voltage, then power consumption decreases, but the manufacturing complexity and formulation difficulty increase

Engineering Contradiction:
Improveoperating voltageVSAvoidformulation complexity
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

The patent changes the dielectric anisotropy parameter by introducing compounds of formula I with specific molecular structures and alkyl substitutions. These compounds provide high dielectric anisotropy values that enable lower operating voltages while maintaining manufacturability through well-defined chemical structures and straightforward synthesis routes.

Inventive Principle:
Principle #35Parameter changes

3Speed

If LC media are optimized for fast response times with lower viscosity, then addressing speeds improve, but the stability and reliability of the display operation deteriorate

Engineering Contradiction:
Improveresponse timeVSAvoidoperational stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent employs composite materials by combining low-viscosity compounds of formula I with other LC compounds in a balanced formulation. This composite structure maintains fast response times through the low-viscosity component while the overall mixture achieves operational stability through the synergistic interaction of multiple compounds with complementary properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by optimizing specific molecular characteristics (alkyl chain lengths R1 and R2 in formula I) to achieve low rotational viscosity in targeted regions of the molecular structure, while the overall LC medium composition maintains global stability through balanced formulation of multiple compounds.

Inventive Principle:
Principle #3Local quality

4Temperature

If conventional LC media are used in public information displays and automotive displays, then the display systems can be implemented with standard components, but the clearing temperature is insufficient and low temperature stability is poor

Engineering Contradiction:
Improveclearing temperatureVSAvoidlow temperature stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the thermal parameters of the LC medium by incorporating compounds of formula I with specific alkyl group configurations. These structural modifications elevate the clearing temperature to suitable levels for public and automotive displays while simultaneously improving low-temperature stability through optimized molecular packing and phase transition characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The LC medium achieves a wide nematic phase range, high reliability, low rotational viscosity, and fast response times, addressing the limitations of previous media and enhancing display performance in various applications.

Implementation Method 1

LC medium with positive dielectric anisotropy

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

utilise an electric field which is substantially perpendicular to the substrates or the LC layer

Methodology Applied
Scientific EffectElectric field: Electric Field

Implementation Method 3

an appropriate birefringence (Δn)

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentUS11739267B2LC medium
Publication Date: 2023.08.29 MERCK PATENT GMBH
  • US11739267B2 patent drawing
  • US11739267B2 patent drawing
  • US11739267B2 patent drawing

AI summary

LC media and LC displays containing an LC medium with positive dielectric anisotropy, which contains one or more compounds of formula I in a concentration of >0 and ≤10%and displays addressed by an active matrix and in particular displays of the IPS, PS-IPS, FFS, PS-FFS, HB-FFS, U-IPS, TN, PS-TN, STN or TN-TFT mode.