Light Conversion Layer Dispersion for LCD Inkjet Printing

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Solution Overview

Problem

Current inkjet ink compositions for liquid crystal display elements face challenges with light leakage, reduced luminescence efficiency, and color reproduction due to aggregation of light-emitting nanocrystals and limited dispersibility, especially when using ultraviolet-curable inks or organic solvent-based systems.

Innovation Solution

A dispersion containing light-emitting nanocrystals, a polymeric dispersant with an amine value of 5 mg/KOH g or more, and a stimulation-responsive curable material that cures in response to external stimuli, such as ultraviolet radiation or heat, is used to enhance dispersibility and reduce light leakage, forming a high-efficiency light conversion layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If the concentration of light-emitting nanocrystals in inkjet ink is increased to improve color reproduction and brightness, then the luminescence efficiency is improved, but the dispersibility of nanocrystals deteriorates and they aggregate during storage

Engineering Contradiction:
ImprovebrightnessVSAvoiddispersibility
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

A polymer dispersant is introduced as an intermediary substance between the light-emitting nanocrystals and the inkjet ink medium. This dispersant has specific functional groups that coordinate with the nanocrystal surfaces, preventing aggregation while maintaining high concentration. The dispersant acts as a bridge that stabilizes the nanocrystals in the ink formulation without requiring dilution.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the ink formulation by incorporating specific polymers with controlled molecular weights, functional group densities, and hydrophobic-hydrophilic balances. These parameter changes enable the system to maintain nanocrystal dispersion stability at high concentrations by modifying the interaction forces between nanocrystals and the ink medium.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If ultraviolet-curable ink is used to eliminate drying steps and improve productivity, then the production efficiency is improved, but light leakage occurs due to insufficient curing or resin aggregation

Engineering Contradiction:
Improveproduction efficiencyVSAvoidcuring completeness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention uses a composite ink formulation combining ultraviolet-curable resin with specific polymer dispersants and co-initiators. This composite system ensures complete and uniform curing by multiple initiation mechanisms, preventing light leakage while maintaining high productivity. The composite formulation addresses the weaknesses of single-component UV inks.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Photoinitiators and co-initiators act as intermediaries that facilitate complete UV curing of the ink. These substances absorb UV energy and generate reactive species that trigger polymerization throughout the ink layer, ensuring thorough curing without aggregation and eliminating light leakage issues.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If organic solvent-based ink is used for light-emitting nanocrystals, then the dispersibility is improved, but additional drying steps are required which reduce productivity

Engineering Contradiction:
ImprovedispersibilityVSAvoidproduction efficiency
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The invention changes the physical state parameter of the ink medium from organic solvent to water-based or solvent-free formulation. By adjusting the chemical composition and polarity parameters, the ink achieves nanocrystal dispersibility comparable to organic solvents while eliminating the need for drying steps, thus improving productivity.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If photolithography is used for color filter production, then the manufacturing precision is maintained, but the initial cost increases and material waste occurs

Engineering Contradiction:
Improvepattern accuracyVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention replaces the photolithographic mechanical system with an inkjet printing system. Inkjet technology deposits materials precisely at designated locations without requiring masks or photoresists, achieving comparable pattern accuracy while eliminating material waste and reducing equipment costs. This substitution transforms a material-intensive process into a precision deposition process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces light leakage, improves luminescence efficiency, and maintains color reproduction, resulting in superior performance of liquid crystal display elements with enhanced transmittance and color gamut stability.

Implementation Method 1

a polymeric dispersant having an amine value of 5 mg/KOH g or more

Methodology Applied
Scientific EffectCoordination bonding: Chemical Bonding

Implementation Method 2

a stimulation-responsive curable material that cures in response to external stimuli, such as ultraviolet radiation or heat

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 3

light-emitting nanocrystals, whose particle diameters are approximately nanometers to tens of nanometers... emit bright fluorescence with a small half width and different wavelengths depending on the particle diameter

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 4

By virtue of the quantum size effect and many-electron effect of the light-emitting nanocrystals

Methodology Applied
Scientific EffectQuantum size effect:

Data Source

PatentUS10947403B2Dispersion and inkjet ink composition, light conversion layer, and liquid crystal display element using the dispersion
Publication Date: 2021.03.16 TOPPAN HOLDINGS INC
  • US10947403B2 patent drawing
  • US10947403B2 patent drawing
  • US10947403B2 patent drawing

AI summary

A dispersion contains, as essential ingredients, light-emitting nanocrystals, a polymeric dispersant having an amine value of 5 mg/KOH g or more, and a stimulation-responsive curable material that cures in response to an external stimulus.