LDS Resin Composition Balancing Mechanical Strength and Laser Activity

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Solution Overview

Problem

Conventional resin compositions for laser direct structuring (LDS) are inferior in mechanical strength, such as bending strength, bending modulus, and Charpy impact strength, while maintaining LDS activity.

Innovation Solution

A resin composition comprising 100 parts by weight of a polycarbonate resin component, 10 to 100 parts by weight of a glass filler, and 1 to 30 parts by weight of a laser direct structuring additive, where the polycarbonate resin consists of 80 to 30% by weight of polycarbonate resin and 20 to 70% by weight of styrene-based resin, with the LDS additive containing antimony, and optionally including talc, polyorganohydrogensiloxanes, and a phosphorus-based stabilizer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the amount of glass filler is increased to enhance mechanical properties, then mechanical strength is improved, but LDS activity is lowered

Engineering Contradiction:
Improvemechanical strengthVSAvoidLDS activity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention optimizes the quantitative parameters of the composition by specifying precise ranges: glass filler at 10-100 parts by weight and LDS additive at 1-30 parts by weight relative to 100 parts of polycarbonate resin component. This parameter optimization balances the competing requirements of mechanical strength and LDS activity, resolving the contradiction between enhancing mechanical properties and maintaining laser direct structuring capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system combining polycarbonate resin, glass filler, and LDS additive in specific proportions. This composite approach allows the glass filler to provide mechanical reinforcement while the LDS additive maintains laser responsiveness, achieving both improved mechanical strength and preserved LDS activity simultaneously

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional resin compositions are used for LDS, then LDS activity is maintained, but mechanical strength is inferior

Engineering Contradiction:
ImproveLDS activityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention develops a composite resin composition that integrates polycarbonate resin component, glass filler, and LDS additive. This composite formulation achieves superior mechanical strength while maintaining LDS activity, overcoming the limitations of conventional single-phase resin compositions used for LDS applications

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin composition achieves enhanced mechanical strength while maintaining LDS activity, enabling the formation of metallic structures like antennas on resin substrates without adhesives.

Implementation Method 1

a surface of a resin-molded article containing an LDS additive is irradiated with a laser, only the portion irradiated with the laser is activated

Methodology Applied
Scientific EffectLaser: Laser

Implementation Method 2

only the portion irradiated with the laser is activated

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS9745465B2Resin composition for laser direct structuring, resin-molded article, and method for manufacturing molded article with plated layer
Publication Date: 2017.08.29 MITSUBISHI ENG PLASTICS CORP
  • US9745465B2 patent drawing
  • US9745465B2 patent drawing
  • US9745465B2 patent drawing

AI summary

Provided is a resin composition excellent in mechanical strength while maintaining LDS activity. The resin composition for laser direct structuring comprises, relative to 100 parts by weight of a polycarbonate resin component, 10 to 100 parts by weight of a glass filler and 1 to 30 parts by weight of a laser direct structuring additive, wherein the polycarbonate resin component consists of 80 to 30% by weight of a polycarbonate resin and 20 to 70% by weight of a styrene-based resin, or consists of a polycarbonate; and the laser direct structuring additive comprises antimony and tin.