Lead-Acid Battery Vapor Barrier for Water Loss Reduction

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Solution Overview

Problem

Lead acid batteries suffer from significant water loss due to evaporation and electrolysis, leading to reduced performance, shorter lifespan, and potential thermal runaway, with existing solutions being costly and ineffective.

Innovation Solution

Incorporating a vapor pressure barrier, such as an oil layer or nonwoven layer, within the battery to reduce water loss by providing an additional surface area for vapor coalescing, creating a tortuous path for gases, and promoting H2/O2 recombination, while using improved battery separators to enhance water retention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If conventional flooded lead acid battery design is used, then manufacturing cost is low and structure is simple, but water loss is significant leading to reduced lifespan and performance

Engineering Contradiction:
Improvewater lossVSAvoidbattery lifespan
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent introduces a hydrophobic coating layer as an intermediary substance between the electrolyte and the separator. This coating acts as a mediator that allows ionic conduction while blocking water vapor transmission, thereby reducing water loss without compromising battery performance or lifespan

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the physical and chemical parameters of the separator by applying a hydrophobic coating that changes its surface properties. The coating alters the separator's wettability and vapor permeability parameters, enabling it to retain water while maintaining ionic conductivity

Inventive Principle:
Principle #35Parameter changes

2Loss of substance

If existing water loss reduction methods are applied, then water retention improves, but manufacturing cost increases significantly

Engineering Contradiction:
Improvewater lossVSAvoidmanufacturing cost
Core Design Contradiction:
Loss of substanceVSEase of manufacture

Solution Approach 1:

The patent employs a cost-effective hydrophobic coating material that can be applied through simple dip-coating or spray methods. The coating uses inexpensive surfactants or hydrophobic polymers that provide effective water loss reduction without requiring expensive specialized materials or complex manufacturing processes

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent achieves water loss reduction by modifying the separator's surface properties through hydrophobic treatment, changing its contact angle and vapor permeability parameters. This parameter modification approach allows using standard separator materials with enhanced performance, avoiding the need for expensive specialized components

Inventive Principle:
Principle #35Parameter changes

3Temperature

If battery operates in high temperature climates, then power output is maintained, but water loss accelerates due to increased evaporation and electrolysis

Engineering Contradiction:
Improveoperating temperatureVSAvoidwater loss
Core Design Contradiction:
TemperatureVSLoss of substance

Solution Approach 1:

The patent converts the harmful effect of high temperature into a beneficial outcome by using heat-curable hydrophobic coatings. The coating is applied in a dormant state and then activated by battery operating temperature, where the heat cures the coating to form a cross-linked network that provides superior water vapor barrier properties

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent utilizes temperature-dependent parameter changes in the hydrophobic coating material. The coating's cross-linking density, glass transition temperature, and free volume parameters change with temperature, optimizing its vapor barrier properties at operating temperatures while maintaining flexibility during assembly

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a substantial reduction in water loss, extending the battery's lifespan and reducing maintenance needs, with laboratory results showing up to 55% less water loss compared to control batteries, thereby improving the battery's performance and longevity.

Implementation Method 1

providing an additional surface area for vapor coalescing

Methodology Applied
Scientific EffectVapor coalescing: Condensation

Implementation Method 2

creating a tortuous path for gases

Methodology Applied
Scientific EffectTortuous path:

Implementation Method 3

promoting H2/O2 recombination

Methodology Applied
Scientific EffectH2/O2 recombination: Catalysis

Implementation Method 4

using improved battery separators to enhance water retention

Methodology Applied
Scientific EffectWater retention: Absorption (physical)

Data Source

PatentUS11916252B2Vapor pressure barriers for lead acid batteries for improved water loss performance, separators, systems, and methods of manufacture and use thereof
Publication Date: 2024.02.27 DARAMIC LLC
  • US11916252B2 patent drawing

AI summary

New or improved lead acid batteries with vapor pressure barriers and/or improved battery separators, as well as systems, vehicles, and/or methods of manufacture and/or use thereof are disclosed herein. In at least select embodiments, the instant disclosure provides new or improved lead acid batteries with a vapor pressure barrier. In at least select embodiments, the instant disclosure provides new or improved lead acid battery vapor pressure barriers along with new or improved battery separators, and/or methods of manufacture and/or use thereof. In at least select embodiments, the instant disclosure provides a new or improved lead acid battery with a vapor pressure barrier that reduces the water loss from the battery. In at least select embodiments, a method of reducing the water loss of a lead acid battery may include providing a vapor pressure barrier, such as a layer of oil, inside the lead acid battery along with an improved battery separator.