Lead-Free Aviation Gasoline Formulations via Hydrocarbon Extraction

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Solution Overview

Problem

Current aviation fuels rely on lead-containing additives to achieve necessary octane levels, which are detrimental to the environment and not compliant with modern regulatory standards, necessitating the development of lead-free formulations that can meet aviation industry fuel standards without engine modifications.

Innovation Solution

The development of novel aviation gasoline formulations comprising dimethylbutane, trimethyl pentane, and isobutane, with optional additives such as m-toluidine, methylcyclopentadienyl manganese tricarbonyl, and alcohols, that do not require lead to achieve sufficient octane ratings, meet ASTM D910 and D909 standards, and are substantially free of hydrocarbon-based aromatics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If lead-containing additives are added to increase octane values, then the octane rating is improved, but environmental harm and regulatory compliance deteriorate

Engineering Contradiction:
Improveoctane ratingVSAvoidenvironmental harm from lead
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent removes lead-containing additives from the aviation gasoline formulation entirely, extracting the harmful substance while maintaining the necessary octane rating through alternative hydrocarbon compositions including dimethylbutane, trimethyl pentane, and isobutane

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters of the fuel by using specific hydrocarbon blends (dimethylbutane 10-40%, trimethyl pentane 50-90%, isobutane 1-5%) to achieve the required octane rating without lead, fundamentally altering how the octane requirement is met

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If hydrocarbon-based aromatics are added to the formulation, then the fuel composition is simplified, but engine carbon deposits and environmental toxicity increase

Engineering Contradiction:
Improveformulation simplicityVSAvoidengine carbon deposits and environmental toxicity
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent explicitly excludes hydrocarbon-based aromatics from the formulation, removing this entire class of compounds to prevent carbon deposit formation and environmental toxicity while maintaining fuel performance through alternative hydrocarbon structures

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a composite hydrocarbon formulation combining multiple specific components (dimethylbutane, trimethyl pentane, isobutane, and optional additives like m-toluidine or MMT) to achieve the desired fuel properties without relying on aromatic hydrocarbons

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS10883061B2Aviation gasoline compositions
Publication Date: 2021.01.05 CALUMET SPECIALTY PRODUCTS PARTNERS LP
  • US10883061B2 patent drawing
  • US10883061B2 patent drawing
  • US10883061B2 patent drawing

AI summary

The present disclosure provides base aviation gasoline formulations. In addition, the present disclosure provides formulations in which one or more additives can optionally be added to the base aviation gasoline formulation to produce a finished aviation gasoline formulation.