Lead-Free Solder Alloy Cobalt Reflectivity

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Solution Overview

Problem

Lead-free solder alloys, such as tin-copper alloys, often appear dull and lack the shiny, reflective surface preferred by the electronics industry, while also being more costly than traditional tin-lead alloys, and do not reliably indicate the presence of impurities.

Innovation Solution

A lead-free solder alloy composed of at least 90% tin, 0.005-5% copper, and 0.005-5% cobalt, which is optimized for wave soldering or hot-air leveling operations, providing a shiny and reflective surface without the use of lead, achieved by adjusting the copper and cobalt concentrations to maintain desired melting points and wettability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If lead-free tin-copper solder alloy is used, then environmental safety and health are improved, but the appearance becomes dull and non-reflective

Engineering Contradiction:
Improveenvironmental safetyVSAvoidsurface reflectivity
Core Design Contradiction:
Object-affected harmful factorsVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the copper content (0.003-0.015 weight percent) and adding cobalt (0.003-0.010 weight percent) to the tin-based alloy. This compositional parameter adjustment resolves the contradiction by achieving both lead-free environmental safety and restored surface reflectivity through optimized alloy chemistry that promotes proper crystalline structure formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining tin with specific amounts of copper and cobalt. This composite approach resolves the contradiction by leveraging the synergistic effects of multiple elements: tin provides the base matrix, copper contributes to strength and controlled reflectivity, and cobalt enhances the shiny appearance while maintaining lead-free composition.

Inventive Principle:
Principle #40Composite materials

2Strength

If tin-copper alloy with silver is used, then strength and electrical properties are improved, but cost increases significantly

Engineering Contradiction:
Improvemechanical strengthVSAvoidmanufacturing cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies this principle by replacing expensive silver with much cheaper copper and cobalt additives. The minimal amounts of copper (0.003-0.015 wt%) and cobalt (0.003-0.010 wt%) provide the necessary strength enhancement at a fraction of the cost of silver, making the alloy economically viable while maintaining lead-free composition.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent uses parameter changes by optimizing the copper content to a very narrow range (0.003-0.015 weight percent) and adding small amounts of cobalt. This precise parameter control achieves strength comparable to or exceeding silver-containing alloys while dramatically reducing material cost through the use of more economical base metals.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If conventional tin-lead alloy is used, then shiny appearance is achieved, but environmental harm and health risks increase

Engineering Contradiction:
Improvesurface reflectivityVSAvoidenvironmental harm
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The patent applies the extraction principle by completely removing lead from the alloy composition while retaining the desirable shiny appearance property. By extracting the harmful lead element and replacing it with a lead-free tin-copper-cobalt system, the patent eliminates environmental and health hazards while preserving the aesthetic quality through careful compositional design.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses parameter changes by adjusting the alloy composition to contain 97.985-99.994 wt% tin, 0.003-0.015 wt% copper, and 0.003-0.010 wt% cobalt. This parameter adjustment achieves lead-free composition while maintaining surface reflectivity through the specific interaction of tin, copper, and cobalt that promotes a shiny crystalline structure.

Inventive Principle:
Principle #35Parameter changes

4Temperature

If tin-copper alloy with higher copper content is used, then melting point is reduced for easier soldering, but appearance becomes duller

Engineering Contradiction:
Improvemelting pointVSAvoidsurface reflectivity
Core Design Contradiction:
TemperatureVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by precisely controlling copper content within a narrow range (0.003-0.015 weight percent) rather than using higher copper concentrations. This controlled parameter adjustment achieves sufficient melting point reduction for easy soldering while preventing excessive copper that would cause dulling, and the added cobalt compensates to maintain surface reflectivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alloy achieves a shiny, reflective appearance similar to traditional tin-lead alloys, while being environmentally friendly and cost-effective, with improved uniformity and reduced thickness in solder coatings, addressing the industry's preference for appearance and safety concerns.

Implementation Method 1

contacting the molten alloy with at least one solid metal piece, and causing or permitting the molten alloy to cool and harden to thereby provide a solder joint

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS9587293B2Lead-free solder alloy
Publication Date: 2017.03.07 ROTHSCHILD STANLEY R
  • US9587293B2 patent drawing
  • US9587293B2 patent drawing
  • US9587293B2 patent drawing

AI summary

A lead-free solder alloy includes a tin-copper alloy that also includes a minor amount of cobalt, which has been found to provide a shiny and reflective appearance to the solder alloy. Methods of soldering using such an alloy, as well as a solder joint including such an alloy also are disclosed.