Lecithin-Based Emulsifier Composition for Soy Polyol Foam Stability

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Solution Overview

Problem

The polyurethane foam industry faces challenges in achieving long-term stability and consistency when using natural oil polyols, particularly soy polyols, due to compatibility issues and phase separation, which requires the development of effective surfactant systems that can solubilize polar solvents in non-polar liquids.

Innovation Solution

A composition comprising lecithin, a plasticizer, and a co-surfactant blend is used to solubilize polar solvents in non-polar liquids, enhancing the solubility and stability of foams produced with natural oil polyols by reducing interfacial tension and improving emulsification properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If natural oil polyols (soy polyols) are used to replace petroleum-based polyols, then environmental friendliness is improved, but foam structure, rigidity, and long-term stability deteriorate due to polarity differences and phase separation

Engineering Contradiction:
Improveenvironmental impactVSAvoidfoam stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent introduces a specific surfactant system comprising a silicone surfactant and a lecithin-based emulsifier as intermediary substances between the polar soy polyol and non-polar foam components. The lecithin emulsifier, derived from natural sources, acts as a mediator that reduces interfacial tension and prevents phase separation, thereby maintaining foam stability while enabling the use of environmentally friendly soy polyols.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a composite surfactant system combining silicone surfactants and lecithin-based emulsifiers to achieve the desired foam properties. This composite approach leverages the hydrophobic characteristics of silicone surfactants and the natural emulsifying properties of lecithin to create a synergistic effect that ensures long-term stability and consistency of foams made with natural oil polyols.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If soy polyols are used instead of petroleum polyols, then polarity and hydroxyl group content are improved, but compatibility with crosslinkers and foam homogeneity worsen

Engineering Contradiction:
Improvehydroxyl group contentVSAvoidfoam homogeneity
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The lecithin-based emulsifier serves as an intermediary that bridges the polarity gap between soy polyols and crosslinkers. By reducing interfacial tension and improving wetting properties, it ensures uniform distribution and compatibility of crosslinkers throughout the foam matrix, preventing phase separation and maintaining homogeneity despite the high polarity of soy polyols.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If lecithin is used without aliphatic solvents, then environmental friendliness is improved, but solubility and functionality of lecithin worsen

Engineering Contradiction:
Improveenvironmental impactVSAvoidlecithin solubility
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent modifies the physical and chemical parameters of lecithin through selection of specific types (e.g., sunflower lecithin, soy lecithin) and forms (liquid or powder) to enhance solubility in foam systems without requiring aliphatic solvents. The invention optimizes lecithin concentration and combines it with silicone surfactants to achieve complete solubility and optimal functionality while maintaining environmental friendliness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The lecithin-based emulsifier system effectively solubilizes polar solvents in non-polar liquids, improving the stability and consistency of foams, allowing for the production of high-quality polyurethane foams with natural oil polyols while reducing environmental impact.

Implementation Method 1

enhancing the solubility and stability of foams produced with natural oil polyols by reducing interfacial tension and improving emulsification properties

Methodology Applied
Scientific EffectInterfacial tension reduction: Surfactant

Implementation Method 2

A composition comprising lecithin, a plasticizer, and a co-surfactant blend is used to solubilize polar solvents in non-polar liquids, enhancing the solubility and stability of foams

Methodology Applied
Scientific EffectEmulsification: Emulsion

Data Source

PatentUS9889417B2Emulsifier for solubilizing polar solvents in oils and polyols
Publication Date: 2018.02.13 ARCHER DANIELS MIDLAND CO
  • US9889417B2 patent drawing

AI summary

The present disclosure is directed to compositions having lecithin, a plasticizer, and an emulsifier. The composition may be used solubilize polar solvents in non-polar liquids. Methods of producing and using the compositions disclosed herein are also disclosed.