Lecithin Microemulsions for Stable Oil Solubilization

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Solution Overview

Problem

Existing oil emulsions, particularly linseed oil emulsions, face challenges in stability due to environmental conditions, leading to limited shelf life and compatibility issues with universal colorants in paint and coating applications, and require high-energy mixing for stabilization.

Innovation Solution

The development of thermodynamically stable microemulsions composed of lecithin, a co-surfactant, and a salt or ester of an acidifier, which can solubilize various oils without high-energy mixing, providing stability and versatility for applications such as cleaning agents, wood preservatives, and coatings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If traditional emulsions are used, then oil and water can be combined, but the emulsion is not kinetically stable and separates under environmental conditions

Engineering Contradiction:
Improveemulsion stabilityVSAvoidshelf life
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent replaces high-energy mechanical mixing with a chemical self-assembly process. The microemulsion forms spontaneously when the surfactant system contacts water and oil, eliminating the need for high-shear mixers or homogenizers. This chemical approach creates thermodynamically stable systems that don't separate under environmental conditions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses a composite surfactant system comprising multiple components (ionic and nonionic surfactants, co-surfactants) that work synergistically. This composite approach creates a more stable microemulsion system than single surfactants, enhancing both kinetic and thermodynamic stability while extending shelf life.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If high-energy mixing is used to stabilize emulsions, then fine droplet sizes are achieved, but the process requires significant energy input

Engineering Contradiction:
Improveemulsion stabilityVSAvoidmixing energy
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by stationary object

Solution Approach 1:

The patent replaces high-energy mechanical mixing with a chemical self-assembly process. The microemulsion forms spontaneously when the surfactant system contacts water and oil, eliminating the need for high-shear mixers or homogenizers. This chemical approach creates thermodynamically stable systems that don't separate under environmental conditions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The surfactant system performs the emulsification function automatically through self-assembly at the oil-water interface. The amphiphilic molecules spontaneously organize themselves to stabilize the interface, eliminating the need for external mechanical energy input to maintain emulsion stability.

Inventive Principle:
Principle #25Self-service

3Adaptability or versatility

If universal colorants are added to water borne systems, then color compatibility is improved, but viscosity changes and pigment separation occur

Engineering Contradiction:
Improvecolorant compatibilityVSAvoidpigment stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent uses the microemulsion system as an intermediary vehicle for pigment dispersion. The surfactant molecules at the oil-water interface provide a stabilizing environment for pigment particles, preventing aggregation and separation. This intermediary phase allows universal colorants to remain stable in water-borne systems while maintaining color compatibility.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microemulsions form instant, stable emulsions upon addition to water, offering cost savings and improved transportation efficiency, with applications in paints, coatings, and other industries, while maintaining stability across a wide temperature range and being tolerant to pH and electrolytes.

Implementation Method 1

The present invention fulfills these needs and discloses microemulsion concentrates and/or microemulsions that are able to solubilize oils

Methodology Applied
Scientific EffectMicroemulsion: Microemulsion

Implementation Method 2

Microemulsions are self-assembled systems, form spontaneously with no high energy mixing, and have excellent stability

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 3

a microemulsion concentrate comprises lecithin, a co-surfactant, and a salt of an acidifier, an ester of an acidifier, or a combination thereof

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 4

microemulsion concentrates and/or microemulsions that are able to solubilize oils

Methodology Applied
Scientific EffectSolubilization: Solvation

Data Source

PatentUS10240112B2Microemulsions and their use in metal working fluids, wood stains, or wood sealers
Publication Date: 2019.03.26 ARCHER DANIELS MIDLAND CO
  • US10240112B2 patent drawing
  • US10240112B2 patent drawing
  • US10240112B2 patent drawing

AI summary

The present disclosure is directed to compositions including a microemulsion comprising a blend of lecithin, a co-surfactant, and a salt of an acidifier, an ester of an acidifier, or combinations thereof. Uses of the compositions are also disclosed.