LED Current Spreading Layer with Metal Nanomaterials

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Solution Overview

Problem

Conventional light-emitting diodes (LEDs) face inefficiencies in current spreading and light extraction due to the refractive index difference between indium tin oxide (ITO) and epoxy resin, leading to concentrated current flow and a small effective light-emitting area.

Innovation Solution

A light-emitting diode structure featuring a current spreading layer doped with conductive metal nanomaterials, such as Ag oxides and Al nanomaterials, which are dispersed within the ITO layer to reduce horizontal resistance and enhance current spreading, combined with a thermal treatment to form metal oxide groups that improve light extraction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If ITO is used as the current spreading layer, then the visible light transmittance is improved (>80%), but the light extraction efficiency deteriorates due to refractive index difference with epoxy resin

Engineering Contradiction:
Improvevisible light transmittanceVSAvoidlight extraction efficiency
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The patent applies composite materials by combining ITO with metal nanomaterial groups (such as Al, Mg, Ga oxides) to create a composite current spreading layer. This composite structure maintains the high visible light transmittance of ITO while introducing materials with refractive indices better matched to epoxy resin, thereby improving light extraction efficiency without sacrificing transmittance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by distributing metal nanomaterial groups locally within the ITO layer rather than uniformly replacing ITO. The metal nanomaterials are dispersed as discrete groups throughout the ITO matrix, creating local regions with enhanced light extraction properties while maintaining the overall high transmittance characteristic of the ITO base material.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If conventional P-type III-V group semiconductor material is used, then the fabrication process is simplified, but the current spreading performance deteriorates

Engineering Contradiction:
Improvefabrication process simplicityVSAvoidcurrent spreading performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies composite materials by creating a current spreading layer that combines ITO (oxide semiconductor) with metal nanomaterial groups. This composite structure achieves superior current spreading performance compared to conventional P-type III-V materials, while the fabrication process remains compatible with standard LED manufacturing techniques such as sputtering and thermal treatment.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by modifying the electrical and optical parameters of the current spreading layer through doping with metal nanomaterials. The metal nanomaterial groups alter the resistivity, carrier concentration, and optical properties of the ITO layer, enabling improved current spreading while maintaining fabrication simplicity through controlled deposition and thermal processing.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If current spreading layer is added over P-type material layer, then the current spreading performance is improved, but the device structure complexity increases

Engineering Contradiction:
Improvecurrent spreading performanceVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by integrating multiple functional components (ITO matrix + metal nanomaterial groups) into a single current spreading layer structure. This composite approach achieves improved current spreading performance while maintaining a relatively simple overall device structure, as the composite layer is deposited as a single thin film rather than requiring multiple separate layers.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies multi-functionality by designing the composite current spreading layer to simultaneously perform multiple functions: current spreading, light extraction enhancement, and optical transparency. The ITO matrix provides transparency and basic current conduction, while the embedded metal nanomaterial groups provide enhanced current spreading and light extraction, eliminating the need for separate functional layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Reliability

If metal nanomaterial groups are doped in current spreading layer, then the horizontal resistance is reduced and current spreading is improved, but the fabrication process complexity increases

Engineering Contradiction:
Improvehorizontal current spreadingVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies merging by combining the deposition of ITO and metal nanomaterials into a single co-sputtering process. Both materials are deposited simultaneously from different targets onto the substrate, creating a composite layer with embedded metal nanomaterial groups in the ITO matrix. This integrated deposition approach reduces fabrication complexity compared to sequential deposition methods.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies parameter changes by controlling the deposition parameters (power ratios, gas flow rates, substrate temperature) during co-sputtering to achieve optimal distribution of metal nanomaterials within the ITO matrix. By adjusting these parameters, the process achieves good current spreading performance while maintaining a relatively simple single-step deposition fabrication process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances current spreading and light extraction efficiency by reducing horizontal resistance and increasing the effective light-emitting area, while maintaining high visible light transmittance and refractive index compatibility with epoxy resin for improved packaging.

Implementation Method 1

a current spreading layer doped with conductive metal nanomaterial groups over the light-emitting epitaxial layer

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

metal nanomaterial groups with high visible light transmittance over the current spreading layer

Methodology Applied
Scientific EffectLight transmission: Light

Implementation Method 3

taking a one-time annealing thermal treatment

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

taking a one-time annealing thermal treatment

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS10205061B2Light emitting diode and fabrication method thereof
Publication Date: 2019.02.12 QUANZHOU SANAN SEMICON TECH CO LTD
  • US10205061B2 patent drawing
  • US10205061B2 patent drawing
  • US10205061B2 patent drawing

AI summary

A light-emitting diode includes from bottom to up: a substrate; a light-emitting epitaxial layer laminated by semiconductor material layers over the substrate; a current spreading layer doped with conductive metal nanomaterial groups over the light-emitting epitaxial layer; and metal nanomaterial groups with high visible light transmittance over the current spreading layer. The conductive metal nanomaterial groups dispersed inside the ITO current spreading layer can reduce horizontal resistance of the current spreading layer and improve horizontal spreading uniformity of current; and metal nanomaterial groups with high visible light transmittance are distributed over the upper surface of the current expansion layer for roughening and increasing light extract efficiency.