III-Nitride LED Electron Blocking Layer Mg Diffusion Barrier

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Solution Overview

Problem

Conventional III-nitride semiconductor light-emitting devices face limitations in achieving improved device lifetime beyond enhancements in external quantum efficiency and resistance characteristics.

Innovation Solution

Incorporating a Si-based doped region layer in the electron blocking layer between the active layer and the p-type semiconductor layer, with optional p-type and undoped region layers, to inhibit the diffusion of Mg and enhance device longevity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Mg is used as a p-type dopant for doping the p-type semiconductor layer, then hole concentration is increased and resistance characteristics are improved, but Mg diffuses into the light emitting layer and deteriorates device lifetime

Engineering Contradiction:
Improvedevice lifetimeVSAvoidMg diffusion into light emitting layer
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an electron blocking layer as an intermediary between the light emitting layer and the p-type semiconductor layer. This layer is doped with Si-based impurities to create a Si-based doped region that acts as a diffusion barrier, preventing Mg from the p-type layer from diffusing into the light emitting layer while still allowing the electron blocking layer to perform its primary function of blocking electrons and improving hole injection efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If an electron blocking layer with high Al content is formed between the light emitting layer and p-type semiconductor layer, then electron blocking capability and hole injection efficiency are improved, but the layer structure becomes more complex

Engineering Contradiction:
Improveelectron blocking capabilityVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions into the electron blocking layer by integrating both the electron blocking function (through high Al content) and the Mg diffusion prevention function (through Si-based doping) into a single layer. This merging approach eliminates the need for separate diffusion barrier layers, thereby reducing overall device complexity while maintaining or improving performance.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If the electron blocking layer is doped with Si-based impurities to prevent Mg diffusion, then device lifetime is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddoping concentration control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies optimal parameter ranges for the Si-based doping in the electron blocking layer, including dopant concentration (1×10^18 to 1×10^20 atoms/cm³) and layer thickness (10 nm to 100 nm). By defining these parameter ranges, the patent provides clear manufacturing guidelines that balance the need for Mg diffusion prevention with the practical constraints of manufacturing precision, making the process controllable and reproducible.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a III-nitride semiconductor light-emitting device with extended device lifetime and maintained light output power, while reducing forward voltage and suppressing reductions in light output.

Implementation Method 1

Mg introduced into the part on the p-type semiconductor layer side by doping diffused into the light emitting layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS10193016B2III-nitride semiconductor light emitting device and method of producing the same
Publication Date: 2019.01.29 DOWA ELECTRONICS MATERIALS CO LTD
  • US10193016B2 patent drawing
  • US10193016B2 patent drawing
  • US10193016B2 patent drawing

AI summary

Provided is a III-nitride semiconductor light-emitting device having excellent device lifetime as compared with conventional devices and a method of producing the same. A III-nitride semiconductor light-emitting device 100 has an n-type semiconductor layer 30, a light emitting layer 40 containing at least Al, an electron blocking layer 50, and a p-type semiconductor layer 60 in this order. The light emitting layer 40 has a quantum well structure having well layers 41 and barrier layers 42. The electron blocking layer 50 is adjacent to the light emitting layer 40 and is formed from a layer having an Al content higher than that of the barrier layers 42 and the p-type semiconductor layer 60. The electron blocking layer 50 has a Si-based doped region layer 50a.