LED Hole Transport Layer Structure for Higher Light Extraction

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Solution Overview

Problem

Current light emitting diodes (LEDs) in display devices face challenges in achieving high emission efficiency and longevity, as existing materials and structures do not effectively optimize light extraction and emission efficiency.

Innovation Solution

A light emitting diode structure is developed with multiple hole transport layers having different refractive indices, specifically a first, second, and third hole transport layer with refractive index differences, to enhance light emission efficiency by minimizing extinction and inducing constructive interference.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a conventional single-layer hole transport structure is used, then the device structure is simple, but the light extraction efficiency is insufficient

Engineering Contradiction:
Improvestructure simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The hole transport region is divided into multiple hole transport layers (first, second, and third hole transport layers) with different refractive indices. This segmentation allows each layer to contribute differently to light extraction, with the high refractive index third layer positioned adjacent to the emission layer to maximize light extraction efficiency while maintaining reasonable structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different hole transport layers are assigned different refractive indices tailored to their specific positions and functions. The third hole transport layer adjacent to the emission layer has a higher refractive index (1.7-2.0) to optimize local light extraction at the emission interface, while other layers have lower refractive indices (1.3-1.6) to maintain overall structural efficiency.

Inventive Principle:
Principle #3Local quality

2Loss of energy

If multiple hole transport layers with different refractive indices are used, then light extraction efficiency is improved, but the device structure becomes more complex

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidstructure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The hole transport region is segmented into three distinct layers with progressively different refractive indices, allowing optimized light extraction without requiring excessive structural complexity. The segmentation is functional rather than arbitrary, with each layer serving a specific optical and electrical transport purpose.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The refractive index parameter is systematically varied across the hole transport layers to optimize light extraction efficiency. By changing this optical parameter rather than structural geometry, the patent achieves improved light extraction without proportionally increasing structural complexity.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If existing materials are used in the emission layer, then material selection is straightforward, but emission efficiency and device longevity are insufficient

Engineering Contradiction:
Improvematerial selection easeVSAvoidemission efficiency and device life
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The emission layer is constructed using composite materials including quantum dots (such as CdSe, CdTe, InP, or perovskite quantum dots) combined with organic or inorganic matrix materials. This composite approach enables tunable emission wavelengths and improved stability, achieving both high emission efficiency and extended device longevity while maintaining reasonable material selection flexibility.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of multiple hole transport layers with varying refractive indices improves light extraction and emission efficiency, leading to higher luminance and extended device life in display devices.

Implementation Method 1

a third hole transport layer disposed between the first hole transport layer and the second hole transport layer, the third hole transport layer having a third refractive index which is greater than each of the first refractive index and the second refractive index

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

to enhance light emission efficiency by minimizing extinction and inducing constructive interference

Methodology Applied
Scientific EffectInterference: Interference

Data Source

PatentUS11744147B2Light emitting diode and display device including the same
Publication Date: 2023.08.29 SAMSUNG DISPLAY CO LTD
  • US11744147B2 patent drawing
  • US11744147B2 patent drawing
  • US11744147B2 patent drawing

AI summary

A light emitting diode of an embodiment includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region. The hole transport region includes a first hole transport layer disposed adjacent to the first electrode and having a first refractive index, a second hole transport layer disposed adjacent to the emission layer and having a second refractive index, and a third hole transport layer disposed between the first hole transport layer and the second hole transport layer and having a third refractive index which is greater than each of the first refractive index and the second refractive index, thereby showing high light extraction efficiency and high emission efficiency properties.