Li-Ion Electrode Assembly Bonding for Adhesion Without Ion Loss
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Solution Overview
Problem
Existing lithium ion secondary batteries face issues with insufficient adhesion between the separator and electrodes, leading to partial detachment, wrinkles, and decreased ionic conductivity, which can cause internal short circuits and capacity loss.
Innovation Solution
A lithium ion secondary battery design featuring a negative electrode with a porous layer containing a polymer binder and inorganic fine particles, bonded to a positive electrode through an adhesive portion made of a thermoplastic polymer with a viscosity of 2000 cPs to 95000 cPs, occupying 0.02% to 10% of the positive electrode area, ensuring adhesion durability without impairing ionic conductivity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If an adhesive is applied to the interface between the electrode and the separator to supplement adhesive force, then adhesion between separator and electrode is improved, but ionic conductivity between electrodes decreases causing capacity loss
Solution Approach 1:
The separator is designed with a porous structure comprising inorganic fine particles (such as aluminum oxide, aluminum hydroxide, magnesium hydroxide, silicon oxide, titanium oxide, or zinc oxide) dispersed in a polymer binder matrix. The porous configuration allows electrolyte to penetrate and flow through the separator, maintaining ionic conductivity while the inorganic particles provide structural integrity and adhesion to the electrode interface without requiring additional adhesive materials that would block ion transport.
Solution Approach 2:
The separator combines inorganic fine particles with a polymer binder to create a composite material structure. This composite approach provides both mechanical adhesion strength through the inorganic particle network and ionic conductivity through the polymer matrix and porous channels, simultaneously addressing both requirements without the need for separate adhesive layers.
2Temperature
If a separator comprising a separator substrate and an inorganic coating layer is used, then thermal stability is improved, but adhesive force between separator and electrode becomes insufficient causing partial detachment or wrinkles
Solution Approach 1:
The separator employs a porous inorganic-coated structure where inorganic fine particles are dispersed throughout the polymer matrix rather than forming a dense coating layer. This porous configuration maintains thermal stability through the inorganic particles while preserving adhesion capability by allowing the polymer binder to interact with the electrode surface and maintain flexible bonding at the interface.
Solution Approach 2:
The separator uses a composite structure where inorganic fine particles are integrated within the polymer binder matrix, creating a unified material that provides both thermal resistance and adhesive properties. The inorganic particles contribute thermal stability while the polymer binder ensures adequate adhesion to the electrode, eliminating the need for a separate coating layer that would compromise adhesion.
3Temperature
If an inorganic coating film is used as the separator to eliminate polyolefin substrate, then thermal stability is improved, but adhesive force with electrode remains insufficient and insulating properties become extremely low causing internal short circuits
Solution Approach 1:
The separator is designed as a composite material where inorganic fine particles are dispersed in a polymer binder matrix. The polymer binder provides the necessary electrical insulation properties to prevent internal short circuits, while the inorganic particles provide thermal stability. This composite approach simultaneously addresses both requirements that failed when using inorganic coating alone.
Solution Approach 2:
The porous structure of the separator, with inorganic particles dispersed in the polymer matrix, maintains electrical insulation through the polymer material while allowing ionic transport through the porous channels. The inorganic particles provide thermal stability without compromising the insulating properties, as the polymer binder continuously surrounds and isolates the conductive inorganic particles.
4Strength
If adhesive is applied to supplement adhesive force, then adhesion between separator and electrode is improved, but battery capacity is reduced due to loss of ionic conductivity
Solution Approach 1:
The porous separator structure allows electrolyte to freely access the electrode interface through the porous network, maintaining efficient ionic conductivity and battery capacity. The inorganic fine particles dispersed in the polymer binder provide adhesion durability at the electrode interface without requiring additional adhesive materials that would block ion transport and reduce battery capacity.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The design achieves excellent adhesion durability between electrodes, maintaining ionic conductivity and preventing internal short circuits, thereby enhancing battery performance and safety.
Implementation Method 1
a positive electrode portion bonded onto the porous layer through an adhesive portion arranged continuously or discontinuously
Implementation Method 2
a porous layer formed on at least one surface of the negative electrode portion, and including a polymer binder and inorganic fine particles dispersed on the polymer binder
Data Source
AI summary
A lithium ion secondary battery includes a negative electrode portion, a porous layer formed on at least one surface of the negative electrode portion, and a positive electrode portion. The porous layer includes a polymer binder and inorganic fine particles dispersed on the polymer binder. The positive electrode portion is bonded onto the porous layer through an adhesive portion arranged continuously or discontinuously. The adhesive portion includes a thermoplastic polymer having a viscosity ranging from 2000 cPs to 95000 cPs at 25° C., and a ratio of an area occupied by the adhesive portion ranges from 0.02% to 10% based on an area of one surface of the positive electrode portion. A lithium ion secondary battery including an electrode assembly which has excellent adhesion durability without impairing ionic conductivity between electrodes is also provided.


