Light-Absorbing Wafer Dicing Mask for Clean Laser-Plasma Singulation

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Solution Overview

Problem

Current semiconductor wafer dicing methods, such as scribing and sawing, often result in chipping, cracking, and waste of wafer real estate due to jagged separation lines and damage to integrated circuits, while plasma dicing faces cost and production issues with metal etching.

Innovation Solution

A method using a water-soluble light-absorbing mask with a femtosecond laser for scribing and subsequent plasma etching to singulate semiconductor wafers, minimizing damage and optimizing etch selectivity with a composite mask that includes light-absorber species and particles for improved etch resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If scribing is used to separate dice, then the separation process is simple and quick, but chipping and cracking occur along the severed edges

Engineering Contradiction:
Improvedicing speedVSAvoidedge integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent segments the dicing process into two distinct stages: laser scribing to create initial separation lines, and plasma etching to complete the separation. This segmentation allows each process to optimize for its specific function, with laser providing speed and plasma providing clean separation without mechanical contact

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent replaces the mechanical diamond scribe with a laser-based system that uses optical energy to ablate material and create separation lines. This substitution eliminates mechanical contact that causes chipping and cracking, while maintaining the speed advantage of scribing

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If sawing is used to separate thicker wafers, then the separation is clean and reliable, but wafer real estate is wasted due to blade thickness and required spacing

Engineering Contradiction:
Improveseparation qualityVSAvoidusable wafer area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent replaces the mechanical saw blade with a laser plasma system that uses optical and plasma energy to etch separation lines. This eliminates the need for physical blade contact, reducing the kerf width from hundreds of microns to micrometer-scale precision, thereby maximizing usable wafer area

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the operating parameters by using laser-induced plasma at controlled energy levels to achieve precise etching. The plasma process parameters (power, gas flow, pressure) are optimized to create clean separations with minimal lateral etching, maintaining separation quality while reducing width

Inventive Principle:
Principle #35Parameter changes

3Reliability

If plasma dicing is used to avoid chipping and cracking, then edge integrity is improved, but cost and production throughput are reduced

Engineering Contradiction:
Improveedge integrityVSAvoidproduction throughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent segments the dicing process into two stages: a rapid laser scribing stage that creates initial separation lines quickly, followed by a plasma etching stage that completes the separation cleanly. This segmentation allows the system to achieve both high throughput (from laser) and high reliability (from plasma)

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The laser scribing performs preliminary action by creating initial separation lines and removing most material before plasma etching. This preliminary action reduces the workload for the plasma process, allowing it to operate at higher power levels for longer durations without compromising throughput, thereby improving edge integrity

Inventive Principle:
Principle #10Preliminary action

4Reliability

If wider spacing is provided between dice to prevent damage, then chip and crack formation is reduced, but wafer real estate is wasted

Engineering Contradiction:
Improvecircuit safetyVSAvoidusable wafer area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent replaces mechanical separation methods with laser-induced plasma etching that operates with micrometer-scale precision. This precision eliminates the need for conservative spacing margins, allowing dice to be placed closer together while maintaining circuit safety from damage

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the separation process parameters to achieve cleaner, more precise cuts with minimal lateral damage zones. By optimizing plasma power, gas composition, and exposure time, the process creates narrow separation lines that maximize usable wafer area while protecting circuits

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces laser damage zones, minimizes chipping and delamination, and enhances etch selectivity, allowing for more efficient and precise dicing with reduced waste and improved integration circuit integrity.

Implementation Method 1

The mask is patterned with a laser scribing process to provide a patterned mask with gaps

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

The substrate is then plasma etched through the gaps in the patterned mask to singulate the integrated circuits

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 3

a mask is formed which includes a water soluble mask material and a light absorber

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Data Source

PatentEP3631848B1Light-absorbing mask for hybrid laser scribing and plasma etch wafer singulation process
Publication Date: 2024.10.16 APPLIED MATERIALS INC
  • EP3631848B1 patent drawingFigure 1
  • EP3631848B1 patent drawingFigure 2A~2C
  • EP3631848B1 patent drawingFigure 3A

AI summary

Light-absorbing masks and methods of dicing semiconductor wafers are described. In an example, a method of dicing a semiconductor wafer including a plurality of integrated circuits involves forming a mask above the semiconductor wafer. The mask includes a water-soluble matrix based on a solid component and water, and a light-absorber species throughout the water- soluble matrix. The mask and a portion of the semiconductor wafer are patterned with a laser scribing process to provide a patterned mask with gaps and corresponding trenches in the semiconductor wafer in regions between the integrated circuits. The semiconductor wafer is plasma etched through the gaps in the patterned mask to extend the trenches and to singulate the integrated circuits. The patterned mask protects the integrated circuits during the plasma etching.