Light-driven Organic Substrate Modification System

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Solution Overview

Problem

Current light-driven biochemical processes for modifying organic substrates are inefficient and costly, requiring high temperatures, catalysts, and hydrogen, and are complex to manufacture, limiting their industrial scalability and application in biofuel production from agricultural waste.

Innovation Solution

A light-driven system comprising a light harvesting molecule, a catalyst, and a reductant or electrochemical electrode that uses sunlight as the primary energy source, significantly increasing catalytic activity and enabling efficient chemical modification of organic substrates, such as cellulose, with minimal external energy input.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional light-driven biochemical processes are used, then chemical modification of organic substrates can be achieved, but the processes require high temperatures, catalysts and hydrogen making them costly and inefficient

Engineering Contradiction:
Improveefficiency of chemical modificationVSAvoidenergy cost and temperature requirement
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent replaces thermal energy input (high temperature heating) with optical energy input (light absorption by chlorophyll). The light-driven photosynthetic system converts photons directly into chemical energy through electron transfer reactions, eliminating the need for thermal processing and external hydrogen supply while achieving the same chemical modification of organic substrates

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system uses abundant biological components (chlorophyll, enzymes, cofactors) that are naturally present in photosynthetic organisms. These components work together in a self-sustaining cycle where light energy drives the reduction of organic substrates using endogenous electron donors, reducing dependence on external catalysts and hydrogen sources

Inventive Principle:
Principle #25Self-service

2Productivity

If hybrid systems with nanocrystals are used for light-driven processes, then catalytic activity can be enhanced, but manufacturing becomes complex and labor-intensive

Engineering Contradiction:
Improvecatalytic activityVSAvoidmanufacturing complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive, complex-to-manufacture nanocrystal catalysts (CdS, TiO2) with abundant, naturally occurring biological components such as chlorophyll molecules and photosynthetic enzymes. These biological catalysts can be obtained through simple extraction from plant or algal materials, dramatically simplifying manufacturing while maintaining catalytic functionality

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The system changes the fundamental parameters of the catalytic system from inorganic nanomaterials requiring precise synthesis conditions to biological macromolecules that can be extracted under mild conditions. This parameter change from synthetic to natural systems resolves the manufacturing complexity issue while preserving catalytic activity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system operates with high efficiency, reducing production costs and enabling the cost-effective conversion of natural resources to energy carriers or chemicals, particularly suitable for biofuel production from agricultural waste, by enhancing the chemical modification process using abundant biological components.

Implementation Method 1

a light harvesting molecule

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

reverse photosynthesis system

Methodology Applied
Scientific EffectPhotosynthesis: Photosynthesis

Implementation Method 3

at least one catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

a reductant and/or an electrochemical electrode

Methodology Applied
Scientific EffectRedox reactions: Redox Reactions

Data Source

PatentUS11680250B2Light-driven system and methods for chemical modification of an organic substrate
Publication Date: 2023.06.20 UNIVERSITY OF COPENHAGEN
  • US11680250B2 patent drawing
  • US11680250B2 patent drawing
  • US11680250B2 patent drawing

AI summary

The present disclosure relates to a light-driven system which is able to chemically modify an organic substrate with high efficiency and in a cost-effective manner. Also provided are methods for chemically modifying an organic substrate using the present systems and methods for manufacturing such systems.