Light-Emitting Device Inorganic Electrode Hole Injection

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Solution Overview

Problem

Conventional light-emitting devices face challenges with high progressive driving voltage, low efficiency, and short lifespan due to limitations in hole injection and interfacial stability between electrodes and hole transport layers.

Innovation Solution

A light-emitting device is designed with a first electrode made of an inorganic material including metals like W, Mo, Ga, Ni, Cu, Zn, and Ti, and a hole transport layer containing a condensed cyclic compound, which enhances hole injection efficiency and interfacial stability, reducing progressive driving voltage and improving lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional organic electrode materials are used, then ease of manufacture is improved, but device stability and lifespan deteriorate

Engineering Contradiction:
Improveease of manufactureVSAvoiddevice stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs composite electrode structures combining organic and inorganic materials. Specifically, the first electrode uses an organic material (e.g., ITO, IZO) as a base and forms an inorganic compound layer (oxides, nitrides, or carbides of W, Mo, Ga, Ni, Cu, Zn, or Ti) on its surface. This composite approach leverages the ease of manufacturing organic electrodes while gaining the superior stability and lifespan of inorganic materials at the critical interface with the hole transport layer.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional hole transport layers are used, then device complexity is reduced, but hole injection efficiency and interfacial stability deteriorate

Engineering Contradiction:
Improvedevice complexityVSAvoidinterfacial stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent applies local quality by concentrating the complexity enhancement at the critical electrode-hole transport layer interface rather than throughout the entire device. The inorganic compound layer is specifically positioned at this interface to provide localized improvement in hole injection efficiency and interfacial stability, while the rest of the device structure remains relatively simple and conventional.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional electrode materials are used, then manufacturing cost is reduced, but progressive driving voltage increases

Engineering Contradiction:
Improvemanufacturing costVSAvoidprogressive driving voltage
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent changes the material parameters at the electrode interface by introducing inorganic compounds with specific properties (high work function, good hole injection capability). This parameter change in the interface material composition enables lower and more stable driving voltage over the device lifetime, while the overall manufacturing process remains compatible with conventional techniques to control costs.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a light-emitting device with low progressive driving voltage, high efficiency, and extended lifespan by improving hole injection and interfacial stability, leading to enhanced performance.

Implementation Method 1

Holes provided from the first electrode move toward the emission layer through the hole transport region

Methodology Applied
Scientific EffectHole injection: Conduction (electrical)

Implementation Method 2

electrons provided from the second electrode move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectCarrier recombination: Electroluminescence

Data Source

PatentUS20230114654A1Light-emitting device and electronic apparatus including the same
Publication Date: 2023.04.13 SAMSUNG DISPLAY CO LTD
  • US20230114654A1 patent drawing
  • US20230114654A1 patent drawing
  • US20230114654A1 patent drawing

AI summary

A light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an interlayer located between the first electrode and the second electrode and including an emission layer, wherein the first electrode includes an inorganic material, the inorganic material includes a metal oxide having, as a main component, at least one metal selected from W, Mo, Ga, Ni, Cu, Zn, and Ti, the interlayer further includes a hole transport region located between the first electrode and the emission layer, the hole transport region includes a hole transport layer, and the hole transport layer includes at least one condensed cyclic compound represented by Formula 1: