Light-Emitting Element Carrier Balance and Lifetime

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Solution Overview

Problem

Current current-excitation light-emitting elements have short lifetimes due to poor durability of hole-blocking layers, leading to inefficient light emission and rapid degradation.

Innovation Solution

A light-emitting element structure is developed with layers for controlling carrier transport, comprising a light-emitting layer sandwiched between a hole-transporting layer and an electron-transporting layer, where the layers contain specific organic compounds with optimized molecular orbital levels and dipole moments to manage hole and electron transport efficiently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a hole-blocking layer is provided to improve light emission efficiency, then light emission efficiency is improved, but durability deteriorates and lifetime becomes very short

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidelement lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent extracts the hole-blocking function from a separate layer and integrates it into the light-emitting layer itself by using a phosphorescent complex that inherently blocks holes while maintaining high light emission efficiency and durability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The phosphorescent complex in the light-emitting layer serves multiple functions simultaneously: it emits light efficiently and blocks hole transport, eliminating the need for a separate hole-blocking layer that would compromise durability

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Device complexity

If carrier transport is not controlled, then device structure is simpler, but carrier balance is poor and lifetime is short

Engineering Contradiction:
Improvelayer structure complexityVSAvoidelement lifetime
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The patent applies local quality by using different organic compounds with specific properties (hole-transporting, electron-transporting, electron-trapping) at different locations within the layers to control carrier transport and achieve carrier balance

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining multiple organic compounds (first organic compound with hole-transporting property, second organic compound with electron-transporting property, third organic compound with electron-transporting property, and fourth organic compound with electron-trapping property) within the layers to achieve controlled carrier transport and improved lifetime

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This structure significantly enhances the lifetime of light-emitting elements by controlling carrier balance and reducing degradation, leading to improved light emission efficiency and reliability.

Implementation Method 1

the first organic compound has a hole-transporting property

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 2

the second organic compound has an electron-transporting property

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

the third organic compound has an electron-transporting property

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 4

the fourth organic compound has an electron-trapping property

Methodology Applied
Scientific EffectElectron trapping: Electrical Resistance

Implementation Method 5

By applying voltage to this element, light can be emitted from the substance having a light-emitting property

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS8803419B2Light-emitting element, light-emitting device, and electronic device
Publication Date: 2014.08.12 SEMICON ENERGY LAB CO LTD
  • US8803419B2 patent drawing
  • US8803419B2 patent drawing
  • US8803419B2 patent drawing

AI summary

It is an object of the present invention to provide a light-emitting element with high light emission efficiency and with a long lifetime. A light-emitting device comprises a first electrode, a second electrode, a light-emitting layer, a first layer, and a second layer, wherein the first layer is provided between the light-emitting layer and the first electrode, the second layer is provided between the light-emitting layer and the second electrode, the first layer is a layer for controlling the hole transport, the second layer is a layer for controlling the electron transport, and light emission from the light-emitting layer is obtained when voltage is applied to the first electrode and the second electrode so that potential of the first electrode is higher than potential of the second electrode.