Light Shielding Film Composition with Low Reflection

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Solution Overview

Problem

Existing light shielding compositions, such as those disclosed in JP2019-082533A, exhibit higher reflectivity than required, necessitating a composition that balances excellent light shielding properties with low reflection properties.

Innovation Solution

A composition comprising carbon black, barium sulfate, copper phthalocyanine or its derivative, a resin, and specific solvents with varying boiling points, along with a polymerization initiator, solvent A with a solubility parameter of 11.0 to 14.0 (cal/cm3)1/2, and optional additives like metal-containing particles and silicone-based surfactants, to form a cured film with improved light shielding and low reflection properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a composition including carbon black and barium sulfate is used for light shielding, then light shielding properties are improved, but reflectivity increases

Engineering Contradiction:
Improvelight shielding propertiesVSAvoidreflectivity
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent uses a composite material system combining carbon black, barium sulfate, and copper phthalocyanine in specific proportions. This multi-component composite achieves both excellent light shielding properties and low reflectivity by leveraging the complementary characteristics of each material: carbon black for light absorption, barium sulfate for refractive index control, and copper phthalocyanine for enhanced optical performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the ratio parameters of the composition components, specifically setting carbon black at 60-80 parts, barium sulfate at 10-30 parts, and copper phthalocyanine at 5-20 parts by mass. This parameter optimization resolves the contradiction by finding the optimal balance point where light shielding is maximized while reflectivity is minimized.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If multiple solvents with different boiling points are used, then film formation and drying properties are improved, but composition complexity increases

Engineering Contradiction:
Improvefilm formation propertiesVSAvoidsolvent system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent selects solvents based on their boiling point parameters, using a first solvent with boiling point 100-150°C and a second solvent with boiling point 150-200°C. This parameter-based selection optimizes film formation during coating and controlled drying without requiring complex solvent blends, resolving the contradiction between film quality and system simplicity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition produces a cured film with enhanced light shielding properties, low reflection, improved pencil hardness, peeling resistance, viscosity stability, and solvent resistance, while maintaining excellent light shielding performance.

Implementation Method 1

a composition including black powder has been used for various purposes... the composition is used in the production of a light shielding film... for the purpose of shielding colored pixels from light

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

a pigment dispersion resist composition for a black matrix with good light shielding properties and low reflectivity, including carbon black, precipitated barium sulfate

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 3

a compound including an unsaturated double bond; and a polymerization initiator

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS12038688B2Composition, light shielding film, solid-state imaging element, image display device, and method for manufacturing cured film
Publication Date: 2024.07.16 FUJIFILM CORP
  • US12038688B2 patent drawing
  • US12038688B2 patent drawing
  • US12038688B2 patent drawing

AI summary

A composition with which a cured film having excellent light shielding properties and low reflection properties can be produced is provided; a light shielding film; a solid-state imaging element; an image display device; and a method for manufacturing a cured film. The composition including carbon black, barium sulfate, one or more kinds selected from the group consisting of copper phthalocyanine and a copper phthalocyanine derivative, a resin, and a solvent, in which the solvent includes a solvent A having a boiling point of 180° C. or higher, a solvent B having a boiling point of 140° C. or higher and lower than 180°° C., and a solvent C having a boiling point of 100° C. or higher and lower than 140° C.