Light-Transmitting Metal Electrode With Segmented Microdomains

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional light-transmitting metal electrodes face challenges with high resistivity and limited transparency due to the trade-off between resistivity and light-transmittance, particularly with oxide semiconductor materials like ITO, which are also facing material shortages and increased costs, and have limitations in carrier density that affect electric conductivity.

Innovation Solution

A light-transmitting metal electrode with a hyperfine structure featuring a metal electrode layer of 10 to 200 nm thickness, comprising continuous metal parts with periodically arranged openings whose distribution is represented by a radial distribution function curve with a half-width of 5 to 300 nm, allowing for high transparency and low resistivity without relying on rare metal oxides.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the thickness of metal foil is increased to improve durability and electrode function, then the mechanical strength and conductivity are improved, but the light-transmittance decreases

Engineering Contradiction:
ImprovedurabilityVSAvoidlight-transmittance
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The metal electrode layer is segmented into multiple discrete metal particles rather than a continuous foil. This segmentation allows light to pass through the gaps between particles while maintaining electrical conductivity through percolation paths, resolving the contradiction between thickness/durability and light-transmittance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The metal layer transitions from uniform continuous structure to a non-uniform distribution of metal particles with varying local concentrations. This creates regions with different properties: areas with sufficient metal content for conductivity and areas with minimal metal for light transmission, allowing both durability and transparency to be achieved simultaneously

Inventive Principle:
Principle #3Local quality

2Reliability

If the carrier density of oxide semiconductor material is increased to improve electric conductivity, then the resistivity is reduced, but the light-transmittance in longer wavelength region decreases

Engineering Contradiction:
Improveelectric conductivityVSAvoidlight-transmittance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The invention replaces expensive oxide semiconductor materials (ITO) with abundant, inexpensive metals. The metal particles provide sufficient conductivity through their inherent high carrier density and mobility, eliminating the need to dope oxide semiconductors to achieve acceptable conductivity levels

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention changes the fundamental material parameter from oxide semiconductor to metal, which has inherently different electrical and optical properties. Metals provide high conductivity without the plasma frequency limitations that constrain oxide semiconductor transparency, allowing simultaneous optimization of both conductivity and light-transmittance

Inventive Principle:
Principle #35Parameter changes

3Reliability

If oxide semiconductor materials like ITO are used to achieve light-transmittance and conductivity, then the electrode function is satisfied, but the cost increases and material exhaustion becomes a problem

Engineering Contradiction:
Improveelectrode functionVSAvoidmaterial availability
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention replaces expensive, scarce oxide semiconductor materials (ITO containing indium) with abundant, inexpensive metals such as aluminum, copper, or silver. These metals are earth-abundant and do not face supply constraints, eliminating both cost and material exhaustion problems while maintaining electrode functionality

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The metal particle-based electrode structure provides universal applicability across different metal choices. The same particle morphology and distribution structure can be used with various metals (Al, Cu, Ag, etc.), allowing selection based on cost or specific performance requirements without changing the fundamental electrode architecture

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS8686459B2Light-transmitting metal electrode and process for production thereof
Publication Date: 2014.04.01 KK TOSHIBA
  • US8686459B2 patent drawing
  • US8686459B2 patent drawing
  • US8686459B2 patent drawing

AI summary

The present invention provides a light-transmitting metal electrode including a substrate and a metal electrode layer having plural openings. The metal electrode layer also has such a continuous metal part that any pair of point-positions in the part is continuously connected without breaks. The openings in the metal electrode layer are periodically arranged to form plural microdomains. The plural microdomains are so placed that the in-plane arranging directions thereof are oriented independently of each other. The thickness of the metal electrode layer is in the range of 10 to 200 nm.