Lignin Particle Separation by Aggregation for Faster Filtration

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Solution Overview

Problem

Existing methods for separating lignocellulose and lignin fractions are costly, inefficient, and result in low filtration rates due to small lignin particle sizes and high operating costs, with dissolved solvents causing additional expenses and filtration complications.

Innovation Solution

A method involving the use of polysaccharides and hydrophobic chemicals to stabilize lignocellulose particles and aggregate lignin particles, followed by mechanical separation techniques such as centrifugation and filtration, to purify lignin and separate lignocellulose fractions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If lignin is precipitated from solution using conventional methods, then pure lignin can be obtained, but filtration rate decreases and operating costs increase due to small particle size

Engineering Contradiction:
Improvepurity of ligninVSAvoidfiltration rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The invention changes the physical-chemical parameters of lignin particles by adjusting pH to isoelectric point and using antifoam agents, which causes particles to aggregate into larger sizes (1-5 mm) that filter much faster while maintaining purity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces intermediary substances (antifoam agents containing hydrophobic chemicals and polysaccharides) that mediate between the lignin particles and the filtration process, causing particles to aggregate and improving filtration without requiring solvent removal

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If dissolvents are used to dissolve and precipitate lignin, then pure lignin can be produced, but operating and capital costs increase due to solvent removal and recovery

Engineering Contradiction:
Improvepurity of ligninVSAvoidoperating cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the dissolvent step from the conventional process by using direct precipitation from aqueous solution with pH adjustment and antifoam agents, removing the need for expensive solvent removal and recovery operations while maintaining lignin purity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces expensive, reusable dissolvents (alcohols, organic acids) with a simple, disposable pH adjustment system using acid or base and antifoam agents, eliminating the need for costly solvent recovery infrastructure

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Quantity of substance

If small lignin particles are produced by conventional precipitation, then lignin can be separated from solution, but dewatering efficiency decreases and energy consumption increases

Engineering Contradiction:
Improvelignin separationVSAvoiddewatering energy
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The invention changes particle size parameters through pH adjustment and antifoam agent addition, transforming fine particles into larger aggregates (1-5 mm) that dewater more efficiently with lower energy consumption and higher dry solids content in filter cake

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If conventional filtration is used on precipitated lignin, then lignin can be separated, but filtration rate decreases due to small particle size

Engineering Contradiction:
Improvelignin separationVSAvoidfiltration rate
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The invention changes the physical parameters of lignin particles by adjusting pH to isoelectric point and adding antifoam agents, causing particles to aggregate into larger sizes (1-5 mm) that achieve filtration rates up to 10 times higher than conventional methods

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves filtration rates and reduces operating costs by enhancing the separation efficiency of lignin and lignocellulose fractions, allowing for higher dry solids content and energy savings in dewatering, while minimizing waste water and increasing the heat value of the compositions.

Implementation Method 1

adding a polysaccharide or modified polysaccharide as stabilizing chemical and/or hydrophobic chemical selected from the group consisting of diesel oil, biodiesel oil, fuel oil, bio fuel oil, kerosene, biokerosene, other middle distillate fraction

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

adding a polysaccharide or modified polysaccharide as stabilizing chemical into the crude lignin

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

treating the crude lignin by separating the lignin particle fraction and lignocellulose particle fraction from each other in at least one solid-solid separation step

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Data Source

PatentEP3094667B1A method and an apparatus for separating lignocellulose particle fraction and lignin particle fraction, a lignin particle composition, a lignocellulose particle composition and their use
Publication Date: 2026.04.15 UPM KYMMENE OYJ
  • EP3094667B1 patent drawingFigure 1
  • EP3094667B1 patent drawingFigure 2
  • EP3094667B1 patent drawingFigure 3

AI summary

The invention relates to a method and an apparatus for separating lignocellulose particle fraction (3) and lignin particle fraction (4), in which crude lignin (1) formed from starting material (6) comprises lignocellulose particles and lignin particles. According to the invention, the method comprises adding stabilizing chemical (11) and/or hydrophobic chemical (12) into the crude lignin (1) in at least one step, and treating the crude lignin by separating the lignin particle fraction (4) and lignocellulose particle fraction (3) from each other in at least one separation step (2,8,9,10). Further, the invention relates to a lignocellulose particle fraction and a lignin particle fraction and their uses.