Lignin-Based Activated Carbon for Impurity Removal

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Solution Overview

Problem

The production of biofuels and biochemicals from lignocellulosic biomass is hindered by impurities introduced during the deconstruction process, which are often removed using energy-intensive and costly techniques, reducing the efficiency and effectiveness of downstream fermentation processes.

Innovation Solution

A method and system utilizing lignin-based activated carbon (LbAC) to adsorb and remove impurities from the hydrolysis stream, produced through a two-step process of pyrolysis and activation of lignin, integrated into the biorefinery process to enhance energy efficiency and reduce wastewater treatment loads.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional impurity removal techniques are used to remove impurities from the hydrolysis stream, then impurity removal effectiveness is improved, but energy consumption and processing cost increase

Engineering Contradiction:
Improveimpurity removal effectivenessVSAvoidenergy consumption
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

Lignin, a byproduct of the hydrolysis process, is converted into activated carbon that is then used to remove impurities from the hydrolysis stream. This self-service approach uses a material generated within the process itself to solve the impurity removal problem, eliminating the need for external energy-intensive treatment processes.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

Instead of discarding lignin as waste, the process recovers and transforms it into activated carbon, a valuable adsorbent material. This recovered activated carbon is then deployed to remove impurities, converting a harmful byproduct into a beneficial resource that reduces overall processing costs and energy requirements.

Inventive Principle:
Principle #34Discarding and recovering

2Object-affected harmful factors

If conventional impurity removal techniques are used, then impurity removal effectiveness is improved, but processing time and operational cost increase

Engineering Contradiction:
Improveimpurity removal effectivenessVSAvoidprocessing time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The system generates its own adsorbent material (activated carbon) from lignin produced during hydrolysis, eliminating the need for external procurement and preparation processes. This self-service mechanism reduces operational complexity and processing time while maintaining effective impurity removal.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

Lignin, normally a waste product requiring disposal, is recovered and transformed into activated carbon. This recovery process creates a functional material that can be immediately applied to impurity removal, reducing both time and cost compared to conventional methods that require separate treatment steps.

Inventive Principle:
Principle #34Discarding and recovering

3Loss of energy

If lignin-based activated carbon is used for impurity removal, then energy efficiency is improved, but process complexity increases

Engineering Contradiction:
Improveenergy efficiencyVSAvoidprocess complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The process merges multiple functions into a unified system: lignin production from hydrolysis, lignin conversion to activated carbon, and impurity removal using the activated carbon. By combining these steps into an integrated process, the system achieves energy efficiency while managing complexity through functional integration rather than separate operations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The recovery and utilization of lignin creates a circular process where a byproduct becomes a resource. This approach adds a transformation step but eliminates the need for external energy-intensive impurity removal processes, netting a reduction in overall process complexity despite the additional lignin conversion step.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of LbAC effectively reduces impurities, enhancing biofuel and biochemical productivity by integrating a self-supporting and energy-efficient impurity removal process that decreases the overall toxicity and processing loads within the biorefinery, allowing for optimized on-site manufacturing of adsorbents tailored to specific downstream bioconversion techniques.

Implementation Method 1

lignin-based activated carbon (LbAC) to adsorb and remove impurities from the hydrolysis stream

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

produced through a two-step process of pyrolysis and activation of lignin

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS12116642B2Lignocellulosic biomass treatment methods and systems for production of biofuels and biochemicals
Publication Date: 2024.10.15 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US12116642B2 patent drawing
  • US12116642B2 patent drawing
  • US12116642B2 patent drawing

AI summary

The present disclosure relates to methods and systems for converting biomass comprising lignocellulosic material into biofuels and biochemicals that contribute to reduction of greenhouse gas emissions. In particular, the present disclosure relates to methods and systems for the removal or reduction of impurities during lignocellulosic biomass processing to enhance biorefinery production of biofuels and biochemicals.