Lime-Based Refining Agent for Hot Metal Dephosphorization

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Solution Overview

Problem

Current dephosphorization methods using a hot metal ladle are inefficient without CaF2-based flux, resulting in a lower dephosphorization rate compared to methods using CaF2-based flux.

Innovation Solution

A method employing a lime-based refining agent with an Ig-loss value of 4.0% to 35% by mass, containing 60% or more quick lime, is used for dephosphorization treatment, where the refining agent is injected with a carrier gas from an immersed lance, and gaseous oxygen is blown to enhance slag formation and reaction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If CaF2-based flux is used to improve slag melting properties, then dephosphorization reactivity is improved, but treatment cost increases and environmental burden increases

Engineering Contradiction:
Improvedephosphorization reactivityVSAvoidslag generation
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The invention changes the chemical composition parameters of the refining agent by specifying an Ig-loss value of 4.0-35% and quick lime content of 60% or more, which fundamentally alters the slag formation characteristics and enables efficient dephosphorization without CaF2-based flux

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts and eliminates the need for CaF2-based flux from the refining process, achieving dephosphorization efficiency improvement through optimized lime-based refining agent composition and properties alone

Inventive Principle:
Principle #2Taking out (Extraction)

2Ease of manufacture

If existing converter is used for dephosphorization treatment, then facility cost is reduced, but dephosphorization efficiency is insufficient

Engineering Contradiction:
Improvefacility costVSAvoiddephosphorization efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention optimizes the parameters of the refining agent (Ig-loss value and quick lime content) to achieve superior dephosphorization efficiency in existing hot metal treating facilities without requiring converter replacement

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention enables the existing hot metal treating facility to perform efficient dephosphorization treatment by optimizing the refining agent properties, making the facility self-sufficient without external converter equipment

Inventive Principle:
Principle #25Self-service

3Loss of substance

If lime-based refining agent is used without CaF2-based flux, then treatment cost is reduced, but slag melting properties deteriorate

Engineering Contradiction:
Improvetreatment costVSAvoidslag melting properties
Core Design Contradiction:
Loss of substanceVSTemperature

Solution Approach 1:

The invention changes the chemical composition parameters of the refining agent by specifying an Ig-loss value of 4.0-35% and quick lime content of 60% or more, which fundamentally alters the slag formation characteristics and enables efficient dephosphorization without CaF2-based flux

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite refining agent system combining specific proportions of quick lime with controlled Ig-loss properties, achieving both cost reduction and adequate slag melting properties through the synergistic effect of the optimized composition

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly improves dephosphorization efficiency without using CaF2-based flux, reducing slag generation, treatment costs, and foaming, while maintaining effective phosphorus removal from hot metal.

Implementation Method 1

An oxygen source such as gaseous oxygen (an oxygen gas) or a solid iron oxide is supplied as a dephosphorizing agent to the hot metal to oxidize phosphorus in the hot metal with oxygen in the dephosphorizing agent so as to produce phosphorus oxide (P2O5)

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

the refining agent is injected with a carrier gas from an immersed lance

Methodology Applied
Scientific EffectGas flow transport: Advection

Implementation Method 3

gaseous oxygen is blown to enhance slag formation and reaction efficiency

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11542566B2Method for dephosphorization of hot metal, and refining agent
Publication Date: 2023.01.03 JFE STEEL CORP
  • US11542566B2 patent drawing

AI summary

When performing dephosphorization treatment of hot metal by adding a refining agent as a lime source and an oxygen source (dephosphorizing agent(s) and a gaseous oxygen source into the hot metal accommodated in a hot metal holding container, the refining agent used is a refining agent having an Ig-loss value of from 4.0% by mass to 35.0% by mass and including 60% by mass or more of quicklime.