Liquid Additive Formulation for Polyester Melt Processing

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Solution Overview

Problem

Current methods for incorporating additives into polymeric materials, such as polyester fibers, face challenges including time-consuming post-production dyeing processes, difficulties with masterbatch handling, and potential detrimental effects on material properties due to carrier degradation and die head pressure issues.

Innovation Solution

A liquid formulation comprising an additive and a vehicle with specific properties, such as high flash point and weight retention, is used to introduce the additive into the polymeric material during melt-processing, ensuring compatibility and minimal impact on fiber tenacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If post-production bath dyeing or spin dyeing is used to incorporate additives into fibres, then the additive can be introduced into the fibre, but the process requires large volumes of liquid additive formulations, is time-consuming, and requires drying of the fibre

Engineering Contradiction:
Improvevolume of liquid additive formulationVSAvoidprocessing time
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The invention changes the physical state of the additive from liquid to solid by converting it into a masterbatch formulation. This transformation eliminates the need for large volumes of liquid formulations and subsequent drying steps, directly addressing both the quantity of substance and productivity parameters.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The additive is pre-incorporated into the masterbatch before the dyeing process. This preliminary action allows the additive to be introduced along with the dyeing operation itself, eliminating the need for separate drying steps and reducing overall processing time.

Inventive Principle:
Principle #10Preliminary action

2Quantity of substance

If masterbatch is used to introduce additives into polymer, then additive incorporation is achieved, but cleaning of the extruder is time-consuming and dosing and handleability of solid pelletized masterbatch can be challenging

Engineering Contradiction:
Improveadditive incorporation efficiencyVSAvoiddosing and handleability
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The invention changes the physical state of the masterbatch from solid pellets to liquid form. This parameter change dramatically improves dosing precision and handleability while maintaining effective additive incorporation, directly addressing the ease of operation parameter.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If liquid formulation with carrier medium is used to incorporate additive into polymer melt, then additive incorporation is achieved, but carrier degradation, die head pressure drop, fuming at the die head and poor properties of polymeric material occur

Engineering Contradiction:
Improveadditive incorporation efficiencyVSAvoidcarrier degradation and fuming
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and eliminates the carrier medium from the liquid formulation. By removing the carrier component that causes degradation and fuming, the system achieves additive incorporation without the harmful side effects, directly addressing the object-affected harmful factors parameter.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses a carrier-free liquid formulation where the additive itself serves as the medium. This eliminates the need for separate carrier substances that would degrade and cause fuming, effectively removing the source of harmful factors.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for efficient and stable incorporation of additives into polymeric materials without significant detrimental effects on properties, reducing processing time and avoiding issues like fuming and carrier degradation, while maintaining high fiber tenacity.

Implementation Method 1

contacting the liquid formulation with said polymeric material

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

melt-processing said polymeric material

Methodology Applied
Scientific EffectMixing:

Data Source

PatentUS11124896B2Polymeric materials
Publication Date: 2021.09.21 COLORMATRIX HOLDINGS INC
  • US11124896B2 patent drawing
  • US11124896B2 patent drawing
  • US11124896B2 patent drawing

AI summary

Additives such as colourants may be incorporated into polymeric materials such as polyesters, such as in polyester fibre production, by use of a liquid formulation comprising colourant and a vehicle. The vehicle may comprise a functionalised pentaerythritol, trimethylolpropane or trimellitate. The liquid formulation is suitably contacted with the polymeric material in a melt processing apparatus.