Liquid Composition for Porous Resin via Phase Separation

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Solution Overview

Problem

Existing porous medium forming methods face challenges in maintaining stable dispersion of fine particles and compatibility issues between polymerizable compounds and solvents, limiting material selection and application versatility.

Innovation Solution

A liquid composition comprising a polymerizable compound and a solvent with high compatibility, capable of forming a porous resin, where the solvent becomes incompatible with the polymerized resin, allowing for phase separation and forming a porous structure with a network structure, enhancing porosity and chemical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If fine particles are used to form porous medium, then porosity is improved, but dispersion stability deteriorates

Engineering Contradiction:
ImproveporosityVSAvoiddispersion stability
Core Design Contradiction:
ShapeVSStability of the object's composition

Solution Approach 1:

The invention changes the physical state of the porous medium from solid particles to a liquid composition containing polymerizable compounds. This parameter change allows the porous structure to be formed through phase separation during polymerization rather than relying on particle dispersion, thereby improving both porosity and dispersion stability simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention utilizes phase transition during polymerization where the polymerizable compound transitions from a homogeneous liquid state to a separated phase, creating porosity. This phase transition mechanism replaces the need for particle dispersion while achieving the desired porous structure with inherent stability

Inventive Principle:
Principle #36Phase transitions

2Ease of manufacture

If polymerizable compound and solvent are mixed, then ease of manufacture is improved, but compatibility deteriorates

Engineering Contradiction:
Improveease of manufactureVSAvoidcompatibility
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The invention performs preliminary action by selecting specific polymerizable compounds and solvents that are pre-determined to be compatible based on their chemical structure characteristics. This preliminary selection ensures both ease of manufacture through simple mixing and maintenance of compatibility, avoiding phase separation before polymerization

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the chemical parameters of the polymerizable compound and solvent to achieve optimal compatibility. By adjusting molecular structure parameters and chemical composition, the system achieves both easy manufacturability and stable compatibility throughout the process

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If material selection is restricted, then compatibility is improved, but adaptability deteriorates

Engineering Contradiction:
ImprovecompatibilityVSAvoidadaptability
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The invention establishes universal selection criteria based on chemical structure characteristics that can be applied to various polymerizable compounds and solvents. This universal approach allows the system to maintain compatibility while being adaptable to different materials and applications, expanding versatility without sacrificing stability

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the formation of porous resins with improved porosity, chemical resistance, and ease of handling, allowing for various application methods such as inkjet printing, while maintaining stability and reducing material limitations.

Implementation Method 1

a polymerizable compound and a solvent, wherein the liquid composition, when stirred, transmits at least 30 percent of incident light having a wavelength of 550 nm and wherein, when an element containing the liquid composition is cured, the haze value of the element increases by 1.0 percent or more

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

the solvent becomes incompatible with the polymerized resin, allowing for phase separation and forming a porous structure with a network structure

Methodology Applied
Scientific EffectPhase separation: Phase Change

Data Source

PatentEP4393968A1Liquid composition and device
Publication Date: 2024.07.03 RICOH CO LTD
  • EP4393968A1 patent drawingFigure 1
  • EP4393968A1 patent drawingFigure 2
  • EP4393968A1 patent drawing

AI summary

A liquid composition that contains a polymerizable compound and a solvent, and that can form a porous resin. The liquid composition, when stirred, transmits at least 30 percent of incident light having a wavelength of 550 nm. The haze value of an containing the liquid composition increases by 1.0 percent or more when the element containing the liquid composition is cured.