Liquid Crystal Alignment Solution for Residual Image Reduction

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Solution Overview

Problem

Conventional liquid crystal display devices face issues with residual images due to incomplete separation of ionic electrons from the alignment layer when the voltage is interrupted, affecting the performance and reliability of the display.

Innovation Solution

A liquid crystal alignment solution comprising a combination of first and second polyimide-polyamide acids with different imidization rates, where the second polyimide-polyamide acid has a side chain, is used to form a stable pre-tilt angle and uniform orientation, enhancing the voltage holding ratio and reducing residual direct current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single polyimide-polyamide acid is used to form the alignment layer, then the manufacturing process is simple, but the pre-tilt angle stability and voltage holding ratio are insufficient

Engineering Contradiction:
Improvepre-tilt angle stabilityVSAvoidalignment solution composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite alignment solution containing two different polyimide-polyamide acids with distinct imidization rates. The first polyimide-polyamide acid (with imidization rate ≤50%) provides stable pre-tilt angle, while the second polyimide-polyamide acid (with imidization rate ≥50%) ensures uniform orientation and high voltage holding ratio. This composite material approach resolves the contradiction by combining materials with complementary properties to achieve both reliability and performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional polyimide materials are used, then the chemical resistance and thermal stability are good, but residual images occur due to incomplete separation of ionic electrons

Engineering Contradiction:
Improveresidual image reductionVSAvoidionic electron accumulation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the alignment layer by incorporating two polyimide-polyamide acids with different imidization rates and molecular structures. This parameter change modifies the surface properties and charge separation characteristics of the alignment layer, enabling more effective separation of ionic electrons and reducing residual image effects while maintaining the inherent chemical resistance and thermal stability of polyimide materials.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If the imidization rate is increased to improve orientation uniformity, then the rubbing property improves, but the pre-tilt angle stability decreases

Engineering Contradiction:
Improveorientation uniformityVSAvoidpre-tilt angle stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent segments the alignment solution into two distinct polyimide-polyamide acid components with different imidization rates. The first component (lower imidization rate ≤50%) is responsible for providing stable pre-tilt angle, while the second component (higher imidization rate ≥50%) is responsible for ensuring uniform orientation and good rubbing properties. This segmentation allows each component to optimize its specific function without compromising the other, resolving the contradiction between orientation uniformity and pre-tilt angle stability.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a liquid crystal display device with improved pre-tilt angle stability, high voltage holding ratio, reduced residual direct current, and enhanced reliability, addressing the issue of residual images and improving overall display performance.

Implementation Method 1

The orientation of liquid crystal molecules is changed as an electric field changes so as to control the light transmitted through the liquid crystal layer to produce an image. The material which can orient liquid crystal molecules at a pre-tilt angle is called an alignment layer.

Methodology Applied
Scientific EffectMolecular alignment:

Implementation Method 2

Conventionally, when a voltage is applied to a liquid crystal display device, the ionic electrons are absorbed by the alignment layer.

Methodology Applied
Scientific EffectIon absorption: Absorption (physical)

Data Source

PatentUS7914863B2Liquid crystal alignment solution
Publication Date: 2011.03.29 DAXIN MATERIALS
  • US7914863B2 patent drawing
  • US7914863B2 patent drawing
  • US7914863B2 patent drawing

AI summary

A liquid crystal alignment solution is provided. The liquid crystal alignment solution includes a first polyimide-polyamide acid and a second polyimide-polyamide acid. The first polyimide-polyamide acid is represented by formula (A),and the second polyimide-polyamide acid is represented by formula (B),in which T1, T2, T3 and T4 are each independently a tetravalent residue of a tetracarboxylic acid dianhydride; D1, D2, D3 and D4 are each independently a divalent residue of a diamine; and m, n, p and q are each independently an positive integer, wherein m/(m+n)≦0.5 and p/(p+q)≧0.5.