Liquid Crystal Chlorine Sensor with Metal Cation Substrate

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Solution Overview

Problem

Current chlorine detection methods are either bulky and heavy, unable to detect chlorine at low concentrations, or require high temperatures, making them unsuitable for wearable sensors or integration into unmanned vehicles, and no liquid crystal-based sensor design can detect chlorine gas effectively.

Innovation Solution

Development of liquid crystal-based sensors using substrate surfaces with metal cations like Mn2+ or gold, where the metal cations or sensitizer molecules facilitate a change in liquid crystal orientational ordering in response to chlorine gas, allowing for detection at concentrations as low as 1 ppm without the need for electrical power or complex equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If gas chromatography or chemical tubes are used for chlorine detection, then detection accuracy is improved, but device complexity and weight increase

Engineering Contradiction:
Improvedetection accuracyVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts the detection function from complex instruments like gas chromatography and chemical tubes, creating a simplified sensor system using liquid crystal composition that maintains detection capability while eliminating unnecessary complexity and weight

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces traditional mechanical/electrical detection systems with an optical-based liquid crystal system that detects chlorine through optical property changes, eliminating the need for complex mechanical components and power systems

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If complex metal oxide thin film is used for chlorine detection, then detection sensitivity is improved, but operating temperature increases

Engineering Contradiction:
Improvedetection sensitivityVSAvoidoperating temperature
Core Design Contradiction:
Measurement precisionVSTemperature

Solution Approach 1:

The patent changes the operating parameters of the detection system by using liquid crystal composition that operates at room temperature instead of high temperatures, while maintaining detection sensitivity through the liquid crystal's response to chlorine-induced surface changes

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If traditional chlorine sensors are used, then detection capability is improved, but weight and size increase

Engineering Contradiction:
Improvedetection capabilityVSAvoidsensor weight
Core Design Contradiction:
Measurement precisionVSWeight of moving object

Solution Approach 1:

The patent uses thin film substrates coated with liquid crystal composition, creating a lightweight and compact sensor structure that maintains detection capability while significantly reducing weight and size compared to traditional sensors

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent creates a simplified model of chlorine detection using liquid crystal optical properties instead of complex sensor mechanisms, achieving detection functionality with minimal weight through the optical response of the liquid crystal layer

Inventive Principle:
Principle #26Copying

4Speed

If electrical sensors are used for chlorine detection, then detection speed is improved, but power consumption increases

Engineering Contradiction:
Improvedetection speedVSAvoidpower consumption
Core Design Contradiction:
SpeedVSUse of energy by moving object

Solution Approach 1:

The patent creates a self-service detection system where the liquid crystal composition automatically responds to chlorine presence through optical property changes, eliminating the need for external power sources while maintaining rapid detection capability

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces electrical sensing mechanisms with an optical-based liquid crystal system that provides rapid detection through natural optical property changes, eliminating power consumption while maintaining detection speed

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the creation of lightweight, inexpensive, and power-independent chlorine sensors that can detect chlorine gas at low concentrations, suitable for wearable devices and unmanned vehicles, providing accurate and deployable detection in various environments.

Implementation Method 1

the liquid crystal composition changes its orientational ordering in response to chlorine gas

Methodology Applied
Scientific EffectLiquid crystal orientational ordering change: Liquid Crystals

Implementation Method 2

substrate surfaces with metal cations like Mn2+ or gold, where the metal cations or sensitizer molecules facilitate a change

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10928306B2Functional surfaces for liquid crystal-based detection of chlorine gas
Publication Date: 2021.02.23 WISCONSIN ALUMNI RES FOUND
  • US10928306B2 patent drawing
  • US10928306B2 patent drawing
  • US10928306B2 patent drawing

AI summary

Liquid crystal-based devices for detecting chlorine in a sample and methods of using such devices to detect chlorine are disclosed. Such devices have a substrate surface that includes either metal cations or a metal that is in contact with a composition that includes a liquid crystal. When the device is contacted with a sample that contains chlorine, an observed change in the orientational ordering of the liquid crystal signals the presence of the chlorine. In the absence of chlorine, no change in orientational ordering occurs.