Liquid Crystal Composition Photostability and Response Speed

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Solution Overview

Problem

Liquid crystal display devices face challenges in achieving high voltage holding ratio and high-speed response characteristics due to the poor photostability of certain compounds used in the liquid crystal layer, which are deteriorated during ultraviolet exposure processes, leading to decreased performance.

Innovation Solution

Incorporating a liquid crystal composition that includes compounds represented by Formula 1 and reactive mesogens, such as those described by Formula RM1 and RM2, which provide improved photostability and thermal stability, while excluding compounds like those in Formula A and B that are prone to deterioration, to maintain the voltage holding ratio and enhance response characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If compounds represented by Formula A are used in the liquid crystal layer, then response speed is improved, but photostability deteriorates during ultraviolet exposure

Engineering Contradiction:
Improveresponse speedVSAvoidphotostability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the liquid crystal compounds by introducing compounds with specific molecular structures (Formula 1, 1-1, 1-2) that have different photostability characteristics compared to conventional compounds (Formula A). This structural parameter change allows maintaining fast response speed while improving resistance to ultraviolet-induced deterioration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid crystal composition by combining multiple liquid crystal compounds (Formula 1, 1-1, 1-2) with reactive mesogens (Formula RM1, RM2) in specific ratios. This composite approach synergistically combines the fast response characteristics of certain compounds with the improved photostability of others, achieving both speed and reliability

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional liquid crystal compounds are used, then manufacturing is simpler, but voltage holding ratio decreases due to deterioration

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidvoltage holding ratio
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the liquid crystal layer by selecting specific compounds (Formula 1, 1-1, 1-2) that inherently resist ultraviolet degradation. This changes the material parameters to maintain voltage holding ratio without complicating the manufacturing process, as the new compounds are used in the same ultraviolet exposure workflow

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional liquid crystal compounds that deteriorate during ultraviolet exposure with more stable alternative compounds. This substitution is analogous to replacing short-lived, degradation-prone materials with longer-lived, stable materials, maintaining manufacturing simplicity while improving long-term reliability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution results in a liquid crystal display device with improved voltage holding ratio and high-speed response characteristics, ensuring better reliability and performance by using stable compounds that resist deterioration during ultraviolet exposure.

Implementation Method 1

the liquid crystal layer includes at least one compound represented by Formula 1 below, and the liquid crystal layer does not include a compound represented by Formula A below

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

the liquid crystal layer disposed between the display panel and the counter display panel and having negative dielectric anisotropy

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Data Source

PatentUS9988576B2Liquid crystal composition and liquid crystal display device
Publication Date: 2018.06.05 SAMSUNG DISPLAY CO LTD
  • US9988576B2 patent drawing
  • US9988576B2 patent drawing
  • US9988576B2 patent drawing

AI summary

A liquid crystal display device comprises a display panel including a first base substrate, a switching element disposed on the first base substrate, a color filter layer disposed on the switching element, and a pixel electrode disposed on the color filter layer; a counter display panel including a second base substrate and a common electrode disposed on the second base substrate and facing the display panel; a liquid crystal layer disposed between the display panel and the counter display panel and having negative dielectric anisotropy, wherein the liquid crystal layer includes at least one compound represented by Formula 1 below, and the liquid crystal layer does not include a compound represented by Formula A below; and a light-blocking spacer disposed on the display panel and including an area overlapping the switching element, and maintaining the thickness of the liquid crystal layer.