Liquid Crystal Composition for VA Displays

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Solution Overview

Problem

Current liquid crystal compositions used in VA display modes suffer from high rotary viscosity, slow response time, and display defects such as residual images and unevenness, particularly in large-sized applications like TVs, due to their dependence on optical anisotropy and drive voltage.

Innovation Solution

A liquid crystal composition comprising specific compounds represented by formulas I, II, III, and others, which enhance dielectric anisotropy, reduce rotary viscosity, and improve clearing point, thereby addressing the issues of response time and display defects by optimizing the dielectric properties and viscosity of the liquid crystal mixture.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid crystal compositions are used in VA display mode, then the display element can achieve wide viewing angle and high contrast, but the rotary viscosity is high and response time is slow

Engineering Contradiction:
Improveresponse timeVSAvoidrotary viscosity
Core Design Contradiction:
SpeedVSForce

Solution Approach 1:

The patent changes the chemical composition parameters of the liquid crystal mixture by incorporating specific compounds (cyclopentyl-containing compounds, fluorinated compounds, and compounds with specific molecular structures as shown in formulas I, II, and III) to optimize the balance between rotary viscosity and response time. The patent specifies precise compositional ranges to achieve the desired performance characteristics.

Inventive Principle:
Principle #35Parameter changes

2Speed

If the liquid crystal composition is optimized for fast response time, then the rotary viscosity decreases, but the clearing point may be compromised

Engineering Contradiction:
Improveresponse timeVSAvoidclearing point
Core Design Contradiction:
SpeedVSTemperature

Solution Approach 1:

The patent creates a composite liquid crystal composition by combining multiple types of compounds with complementary properties: cyclopentyl-containing compounds for viscosity control, fluorinated compounds for thermal stability and clearing point maintenance, and specifically structured compounds (formulas I, II, III) for balanced performance. This composite approach allows simultaneous optimization of response time and clearing point.

Inventive Principle:
Principle #40Composite materials

3Speed

If the liquid crystal composition uses high dielectric anisotropy compounds, then the response speed improves, but display defects such as residual images and unevenness increase

Engineering Contradiction:
Improveresponse speedVSAvoiddisplay defects
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies local quality by specifying particular molecular structure characteristics in different components of the mixture: compounds with specific substituent patterns (R1-R6 groups in formulas I, II, III), cyclopentyl groups at specific positions, and fluorine substitutions at defined locations. This localized structural optimization ensures that each component contributes specific properties that collectively improve response speed while minimizing display defects.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid crystal composition achieves a lower viscosity, faster response time, and reduced display defects, making it suitable for wide viewing angle displays like IPS and VA modes, especially in small to medium-sized displays and TVs.

Implementation Method 1

enhance dielectric anisotropy, reduce rotary viscosity, and improve clearing point, thereby addressing the issues of response time and display defects

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

the contrast of the VA mode display is less dependent on the optical anisotropy (Δn) of the liquid crystal

Methodology Applied
Scientific EffectOptical anisotropy: Birefringence

Data Source

PatentUS11021654B2Liquid crystal composition
Publication Date: 2021.06.01 SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
  • US11021654B2 patent drawing
  • US11021654B2 patent drawing
  • US11021654B2 patent drawing

AI summary

Disclosed is a liquid crystal composition comprising one or more compounds represented by formula I, one or more compounds represented by formula II, and one or more compounds represented by formula III:The liquid crystal composition has simultaneously a lower rotary viscosity, a better photoelectric performance, a higher clearing point, a good low temperature performance, and less display defects. Further disclosed is a liquid crystal display element or device comprising the liquid crystal composition.