Liquid Crystal Composition for VA Mode Displays

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Solution Overview

Problem

Liquid crystal compositions used in VA mode displays have limitations such as smaller dielectricity, slower response time, higher drive voltage, and are prone to display defects like afterimages, necessitating improvements in response speed and defect reduction.

Innovation Solution

A liquid crystal composition comprising specific compounds represented by formulas I, II, and III, along with a polymerizable compound, which enhances dielectric anisotropy, reduces rotary viscosity, and achieves a faster response speed, thereby minimizing display defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If liquid crystal compositions are used in VA mode displays, then wide viewing angle and high contrast are achieved, but response time becomes slow and dielectricity is reduced

Engineering Contradiction:
ImprovecontrastVSAvoidresponse time
Core Design Contradiction:
Illumination intensityVSSpeed

Solution Approach 1:

The patent modifies the molecular structure of liquid crystal compounds by changing parameters such as introducing fluorine atoms at specific positions (R3 and R4 in formula III), adjusting alkyl group lengths (R1-R4 in formulas II and III), and modifying the core structure (formula I). These structural parameter changes optimize the balance between dielectric anisotropy and rotary viscosity, achieving faster response times while maintaining the wide viewing angle and high contrast characteristics of VA mode displays.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite liquid crystal compositions combining multiple compounds with specific functions: compounds of formula I provide the basic liquid crystal properties, compounds of formula II enhance dielectric anisotropy, and compounds of formula III optimize rotary viscosity. This composite approach allows simultaneous optimization of contrast, viewing angle, and response time by leveraging the complementary properties of different molecular structures.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If liquid crystal compositions are used in VA mode displays, then wide viewing angle is achieved, but drive voltage becomes high and display defects increase

Engineering Contradiction:
Improveviewing angleVSAvoiddisplay defects
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent optimizes molecular parameters by introducing fluorine substitutions at specific positions (R3 and R4 in formula III) and adjusting alkyl chain lengths to optimize the balance between dielectric anisotropy and rotary viscosity. This parameter optimization reduces the elastic constant K33 and rotary viscosity γ1, enabling lower drive voltages and reduced display defects such as afterimages while maintaining wide viewing angle characteristics.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If liquid crystal compositions are used in VA mode displays, then wide viewing angle is achieved, but dielectricity becomes small and response speed is slow

Engineering Contradiction:
Improveviewing angleVSAvoiddielectricity
Core Design Contradiction:
Illumination intensityVSUse of energy by moving object

Solution Approach 1:

The patent systematically modifies molecular structures by changing parameters such as introducing fluorine atoms at specific positions (R3 and R4 in formula III), adjusting alkyl group lengths (R1-R4 in formulas II and III), and modifying the core structure (formula I). These parameter changes optimize the dielectric anisotropy Δε and rotary viscosity γ1, achieving faster response times while maintaining the wide viewing angle characteristics of VA mode displays.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite liquid crystal compositions combining multiple compounds with specific functions: compounds of formula I provide the basic liquid crystal properties, compounds of formula II enhance dielectric anisotropy, and compounds of formula III optimize rotary viscosity. This composite approach allows simultaneous optimization of viewing angle, dielectricity, and response time by leveraging the complementary properties of different molecular structures.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides a liquid crystal display with improved response speed, reduced defects, and enhanced dielectric properties, addressing the limitations of existing VA mode displays.

Implementation Method 1

a liquid crystal composition having a low rotary viscosity (γ1), a larger dielectric anisotropy (Δε), and a fast response speed

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

a liquid crystal composition having a low rotary viscosity (γ1), a larger dielectric anisotropy (Δε), and a fast response speed

Methodology Applied
Scientific EffectRotary viscosity: Viscometer

Data Source

PatentUS11242487B2Liquid crystal composition, liquid crystal display element and liquid crystal display
Publication Date: 2022.02.08 SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
  • US11242487B2 patent drawing
  • US11242487B2 patent drawing
  • US11242487B2 patent drawing

AI summary

A liquid crystal composition, and a liquid crystal display element or liquid crystal display comprising the liquid crystal composition, and belongs to the field of liquid crystal display, the liquid crystal composition of the present disclosure comprising a compound represented by formula I, one or more compounds represented by formula II, one or more compounds represented by formula III, and at least one polymerizable compound. The liquid crystal composition simultaneously has a low rotary viscosity (γ1), a larger dielectric anisotropy (Δε), and a fast response speed.