Liquid Crystal Cured Layer Tilt Angle Orientation

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Solution Overview

Problem

It is challenging to achieve the intended orientation state of a liquid crystal compound with a reverse wavelength dispersion property, particularly in increasing the tilt angle of the main chain mesogen with respect to the layer plane, as existing technologies are not effective for compounds with this property.

Innovation Solution

A liquid crystal cured layer is formed using a polymerizable liquid crystal compound with a reverse wavelength dispersion property and a copolymer containing specific monomer units, which promotes the orientation of the main chain mesogen in the thickness direction, achieving a tilt angle of 85° to 90°.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If prior art technology for orienting liquid crystal compound is applied, then orientation in thickness direction can be achieved for forward wavelength dispersion compounds, but orientation cannot be achieved for reverse wavelength dispersion compounds

Engineering Contradiction:
Improveorientation stateVSAvoidapplicability to reverse wavelength dispersion compounds
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent changes the chemical composition parameters of the liquid crystal system by introducing a copolymer containing specific monomer units (monomer unit A with aromatic ring and monomer unit B with aliphatic hydrocarbon group). This compositional parameter change enables the system to achieve orientation in thickness direction for reverse wavelength dispersion compounds, which previously could not be oriented using conventional methods.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If conventional orientation methods are used, then liquid crystal compound can be oriented in plane direction, but tilt angle with respect to layer plane cannot be increased to 85°-90°

Engineering Contradiction:
Improvetilt angleVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The copolymer acts as an intermediary substance that mediates between the liquid crystal compound and the substrate. The copolymer's specific structure (containing both aromatic and aliphatic monomer units) enables it to interact with reverse wavelength dispersion compounds and induce their orientation at high tilt angles (85°-90°) without requiring complex multi-step processing.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If polymerizable liquid crystal compound with reverse wavelength dispersion property is used, then optical properties can be improved, but orientation defects increase without proper orientation aid

Engineering Contradiction:
Improveoptical propertiesVSAvoidorientation uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent creates a composite liquid crystal system comprising the polymerizable liquid crystal compound (with reverse wavelength dispersion property) and the copolymer orientation aid. This composite material approach combines the optical benefits of reverse wavelength dispersion compounds with the orientation capabilities of the copolymer, achieving both high optical quality and uniform orientation without defects.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution allows for the effective orientation of the main chain mesogen in the liquid crystal cured layer, enhancing the orientation properties and reducing orientation defects, thereby improving the optical properties of the layer.

Implementation Method 1

a liquid crystal cured layer formed of a cured product of a liquid crystal composition containing a polymerizable liquid crystal compound

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS11447700B2Liquid crystal cured layer, production method therefor, optical film, polarizing plate, and display device
Publication Date: 2022.09.20 ZEON CORP
  • US11447700B2 patent drawing
  • US11447700B2 patent drawing
  • US11447700B2 patent drawing

AI summary

A liquid crystal cured layer formed of a cured product of a liquid crystal composition, wherein the liquid crystal composition contains a polymerizable liquid crystal compound having a reverse wavelength dispersion property, and a copolymer containing a monomer unit A including a monovalent group containing an aromatic ring and a monomer unit B containing a monovalent aliphatic hydrocarbon group optionally having a substituent, a main chain mesogen of the polymerizable liquid crystal compound in the liquid crystal cured layer is oriented at a tilt angle of 85° to 90° with respect to a layer plane of the liquid crystal cured layer.