Liquid Crystal Medium for VA Displays with Fast Switching

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Solution Overview

Problem

Current liquid crystal mixtures for electro-optical displays, particularly in VA and PSA displays, face challenges with high specific resistance, long switching times, and limited temperature stability, which affect display performance and reliability, especially at extreme temperatures.

Innovation Solution

The use of liquid-crystalline media containing compounds of a specific formula with negative dielectric anisotropy and low rotational viscosity, which enable short switching times and improved temperature stability, along with the incorporation of polymerizable compounds for in-situ polymerization to achieve desired tilt angles and voltage holding ratios.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid crystal mixtures are used in VA and PSA displays, then the displays can be manufactured with standard materials, but the switching times are long and temperature stability is limited

Engineering Contradiction:
Improveswitching timeVSAvoidtemperature stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent modifies the molecular structure of liquid crystal compounds by introducing specific substituents (fluoro, chloro, cyano groups) and adjusting the core structure (cyclohexane, phenyl rings) to change physical parameters such as rotational viscosity and dielectric anisotropy, achieving faster switching times while maintaining temperature stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite liquid crystal mixtures containing multiple compounds with different molecular structures (cyclohexane-based, phenyl-based, ester-based compounds) that work synergistically to achieve both fast switching times and broad temperature stability ranges

Inventive Principle:
Principle #40Composite materials

2Reliability

If liquid crystal mixtures with high specific resistance are used, then image sticking is reduced, but manufacturing precision and control of other properties become more difficult

Engineering Contradiction:
Improveimage sticking resistanceVSAvoidproperty control precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent assigns different functional roles to different molecular components: some compounds contribute primarily to high specific resistance, others to appropriate rotational viscosity, and others to dielectric anisotropy, allowing independent optimization of each property through selective compound inclusion

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent systematically adjusts molecular parameters such as chain length, substituent types, and core structures to fine-tune the electrical and rheological properties of the liquid crystal mixture, achieving precise control over specific resistance and other critical parameters

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If polymerizable compounds are added for in-situ polymerization, then desired tilt angles and voltage holding ratios are achieved, but the mixture complexity increases

Engineering Contradiction:
Improvetilt angle controlVSAvoidmixture complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent combines polymerizable functional groups (acrylate, methacrylate, vinyl) directly into the liquid crystal molecular structures, merging the functions of liquid crystal behavior and polymerization capability into single compounds, thereby simplifying the overall system while maintaining operational control

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent designs liquid crystal compounds that simultaneously provide multiple functions: liquid crystalline phase behavior, desired tilt angle through surface interaction, voltage holding through polymer network formation, and appropriate viscosity, reducing the need for separate additive compounds

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in liquid crystal mixtures with high specific resistance, short switching times, and improved temperature stability, reducing image sticking and enhancing display reliability over long operating periods, while allowing for faster pretilt angle generation without photoinitiators.

Implementation Method 1

liquid-crystalline media containing compounds of a specific formula with negative dielectric anisotropy and low rotational viscosity, which enable short switching times

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

compounds of formula I having very low rotational viscosities γ1, in particular ≤ 165 mPa s, in particular ≤ 140 mPa s

Methodology Applied
Scientific EffectRotational viscosity: Viscometer

Implementation Method 3

incorporation of polymerizable compounds for in-situ polymerization to achieve desired tilt angles and voltage holding ratios

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 4

The principle of electrically controlled birefringence, the ECB effect (electrically controlled birefringence)

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentEP3257916B1Liquid crystalline medium
Publication Date: 2021.11.17 MERCK PATENT GMBH
  • EP3257916B1 patent drawing
  • EP3257916B1 patent drawing
  • EP3257916B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium comprising at least one compound of formula I, R1, R1*, rings A and B, Z1, L1, and L2, a and b having the meanings specified in claim 1, and its use for an active-matrix display, in particular based on the VA, PSA, PS-VA, PALC, FFS, PS-FFS, IPS, and PS-IPS effects.