Liquid Crystal Medium for ECB Displays

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Solution Overview

Problem

Liquid crystal displays using the ECB effect face challenges with high switching times, low specific resistance, and instability under temperature and UV stress, particularly in mobile applications, where they require improved voltage holding ratio and stability.

Innovation Solution

A liquid crystal medium comprising specific compounds, including those of formulas I, II, and III, which provide a broad nematic phase range, high negative dielectric anisotropy, low rotational viscosity, and stability, enabling short switching times and high voltage holding capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid crystal mixtures are used in ECB displays, then the display can operate, but the switching time is too long and specific resistance is insufficient

Engineering Contradiction:
Improveswitching timeVSAvoidspecific resistance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully adjusting the composition ratios and molecular structures of liquid crystal compounds. Specifically, it combines compounds with different dielectric anisotropy values and rotational viscosity characteristics to achieve optimal performance. The mixture contains compounds with negative dielectric anisotropy (Δε ≤ -0.5) in specific proportions to simultaneously reduce switching time while maintaining adequate specific resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by creating a multi-component liquid crystal mixture rather than using a single compound. The mixture includes at least three different liquid crystal compounds with complementary properties: some providing high negative dielectric anisotropy for fast switching, others providing chemical resistance and stability. This composite approach allows the system to achieve multiple performance targets that cannot be met by individual compounds

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If liquid crystal mixtures with high polarity are used to achieve low drive voltages, then voltage holding ratio decreases and stability under temperature and UV stress deteriorates

Engineering Contradiction:
Improvedrive voltageVSAvoidvoltage holding ratio and stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent applies local quality by assigning different functional roles to different components within the liquid crystal mixture. Specifically, certain compounds are selected for their polarity characteristics to enable low drive voltage operation, while other compounds are chosen for their chemical resistance and thermal stability. Each component contributes its specific local property to the overall system, allowing the mixture to achieve low drive voltage without sacrificing stability or voltage holding ratio

Inventive Principle:
Principle #3Local quality

3Speed

If liquid crystal compounds with high negative dielectric anisotropy are used to reduce switching time, then rotational viscosity must be reduced, but this affects stability under temperature and UV stress

Engineering Contradiction:
Improveswitching timeVSAvoidstability under temperature and UV stress
Core Design Contradiction:
SpeedVSObject-affected harmful factors

Solution Approach 1:

The patent uses intermediary compounds as mediators between the high-performance but unstable liquid crystal compounds and the stability requirements. Specifically, it includes compounds with moderate dielectric anisotropy and high chemical resistance that act as stabilizing agents. These intermediary compounds protect the overall mixture from degradation under temperature and UV stress while allowing the high-performance compounds to contribute to fast switching times

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The medium achieves short switching times, high voltage holding ratio, and stability across a wide temperature range, suitable for ECB and IPS displays, particularly in mobile devices.

Implementation Method 1

Liquid crystal displays that utilize the ECB (Electrically Controlled Birefringence) effect with dielectrically negative liquid crystals in a homeotropic output orientation

Methodology Applied
Scientific EffectElectrically controlled birefringence (ECB effect): Birefringence

Implementation Method 2

The principle of electrically controlled birefringence, the ECB effect (electrically controlled birefringence) or DAP effect (deformation of upright phases), was first described in 1971

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 3

The principle of electrically controlled birefringence, the ECB effect (electrically controlled birefringence) or DAP effect (deformation of upright phases), was first described in 1971

Methodology Applied
Scientific EffectDeformation of upright phases (DAP effect): Deformation

Data Source

PatentEP3133137B1Liquid crystalline medium and electro-optic display
Publication Date: 2019.09.18 MERCK PATENT GMBH
  • EP3133137B1 patent drawing
  • EP3133137B1 patent drawing
  • EP3133137B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium with a nematic phase and a negative dielectric anisotropy, which contains a) a compound of formula I and one or more phenol derivatives, b) one or more compounds of formula II, and c) one or more compounds selected from the group of compounds of formulas III-1 to III-4, wherein the parameters have the meanings specified in claim 1, its use in an electro-optical display, particularly in an active-matrix display based on the VA, ECB, PALC, FFS, or IPS effect, such displays containing such a liquid-crystalline medium, and the use of the compound of formula I for stabilizing a liquid-crystalline medium containing one or more compounds of formula II and one or more compounds selected from the group of compounds of formulas III-1 to III-4.