Temperature-Responsive Liquid Crystal Medium for Passive Light Regulation

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Solution Overview

Problem

Current temperature-reactive devices for regulating light transmission through windows or glass surfaces are inefficient, requiring electrical connections, abrupt switching, and lack adaptability to ambient conditions, failing to meet demands for energy efficiency, durability, and aesthetic considerations.

Innovation Solution

A liquid crystalline medium comprising liquid crystalline compounds, dichroic dyes, and self-aligning molecules with three-dimensional structures and anchor groups, which induces homeotropic alignment, allowing for temperature-dependent control of light transmission without electrical switching, ensuring energy efficiency and adaptability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If electrical switching is used to control light transmission, then light transmission can be regulated, but electrical connections are required which reduce energy efficiency and increase device complexity

Engineering Contradiction:
Improveenergy efficiencyVSAvoiddevice complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent replaces electrical switching mechanisms with a temperature-reactive liquid crystalline medium that automatically regulates light transmission in response to ambient temperature changes. This eliminates the need for electrical connections, switches, and control circuits, thereby improving energy efficiency and reducing device complexity while maintaining the light transmission regulation function

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The liquid crystalline medium is formulated to autonomously respond to temperature changes and regulate light transmission without external control. The medium contains compounds that automatically induce homeotropic alignment at specific temperatures, enabling the device to self-regulate light transmission based on ambient conditions without requiring electrical power or complex control systems

Inventive Principle:
Principle #25Self-service

2Adaptability or versatility

If abrupt switching is used for light transmission regulation, then control is achieved, but adaptability to ambient conditions is reduced

Engineering Contradiction:
Improveadaptability to ambient conditionsVSAvoidgradual transitions
Core Design Contradiction:
Adaptability or versatilityVSEase of operation

Solution Approach 1:

The patent utilizes temperature as a continuous parameter to control the optical properties of the liquid crystalline medium. As temperature gradually changes, the medium's molecular alignment transitions smoothly between isotropic and homeotropic states, producing gradual light transmission changes that adapt continuously to ambient temperature conditions rather than abrupt on/off switching

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The liquid crystalline medium dynamically adjusts its molecular alignment in response to changing temperature conditions. The medium transitions from an isotropic state at higher temperatures (allowing light transmission) to a homeotropic aligned state at lower temperatures (blocking light transmission), providing continuous adaptability to ambient conditions through gradual phase transitions

Inventive Principle:
Principle #15Dynamics

3Reliability

If homeotropic alignment is induced using conventional methods, then alignment is achieved, but reliability and durability are reduced

Engineering Contradiction:
ImprovereliabilityVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite liquid crystalline medium containing multiple components including liquid crystalline compounds, dichroic dyes, and homeotropic alignment-inducing compounds. This composite formulation achieves reliable and durable homeotropic alignment without requiring external alignment layers or complex structural features, improving reliability while maintaining simplicity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses specific compounds within the liquid crystalline medium that act as intermediaries to induce homeotropic alignment. These compounds mediate the alignment process by interacting with the liquid crystalline molecules and directing them into a homeotropic configuration in response to temperature changes, achieving reliable alignment without external control mechanisms

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a reliable, energy-efficient, and aesthetically pleasing means of regulating light transmission, adapting to temperature changes with gradual transitions, enhancing durability and reducing maintenance needs.

Implementation Method 1

The switching between a state of relatively high light transmission and a state of relatively low light transmission is achieved by a phase transition of the liquid-crystalline medium from a nematic state to an isotropic state

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 2

one or more compounds capable of promoting or inducing homeotropic alignment to the adjacent liquid crystal medium... The long molecular axes (in case of calamitic compounds) or the short molecular axes (in case of discotic compounds) of a large proportion of the liquid-crystalline molecules are oriented at an angle θ ('tilt angle') between about 80° to 90° relative to the plane of the layer

Methodology Applied
Scientific EffectHomeotropic alignment:

Implementation Method 3

The dichroic dye make use of the dichroic absorption: light with polarization along the absorption transition dipole is absorbed while light with polarization perpendicular to the dipole is not absorbed

Methodology Applied
Scientific EffectDichroic absorption: Absorption (EM radiation)

Data Source

PatentEP2997109B1Liquid crystalline medium and liquid crystal device
Publication Date: 2018.03.21 MERCK PATENT GMBH
  • EP2997109B1 patent drawingFigure 1~2
  • EP2997109B1 patent drawing
  • EP2997109B1 patent drawing

AI summary

The present invention relates a liquid crystalline medium comprising one or more liquid crystalline compounds, one or more dichroic dyes, and one or more compounds capable of promoting or inducing homeotropic alignment to the adjacent liquid crystal medium at a given temperature selected from the group of compounds (A), having a three-dimensional structure, a molecular weight of greater than 450 Da, and one or more anchor groups, or the group of organic compounds (B) having one or more ring groups, and one or more anchor groups. The invention furthermore relates to a temperature-reactive device for the regulation of light transmission, containing such liquid crystalline medium, and a process for the temperature-dependent control of light transmission through the layer of such liquid-crystalline medium.