Liquid Crystal Medium for Fast Switching and Low Voltage

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Solution Overview

Problem

Existing liquid crystal media for displays fail to simultaneously achieve high specific resistance, low threshold voltage, broad nematic phase range, low rotational viscosity, and fast switching times, especially at low temperatures, while maintaining other parameter values.

Innovation Solution

A liquid crystal medium comprising specific compounds (formulas I to VI) in defined percentages, optionally with a HALS-type stabilizer like TINUVIN®770, which provides a broad nematic phase range, low viscosity, and high UV stability, enabling fast switching and low threshold voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid crystal media are used, then the nematic phase range can be maintained, but the specific resistance is insufficient and threshold voltage remains high

Engineering Contradiction:
Improvespecific resistanceVSAvoidmedia composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite liquid crystal medium comprising six different compound classes (formulas I-VI) with specific weight percentage ranges. This composite approach combines compounds with complementary properties: Formula I compounds contribute to dielectric anisotropy, Formula II and III compounds provide nematic phase stability, Formula IV compounds enhance viscosity characteristics, Formula V compounds contribute to optical anisotropy, and Formula VI compounds adjust transition temperatures. The synergistic combination achieves high specific resistance (≥1×10^12 Ω·cm at 20°C) and low threshold voltage simultaneously, which cannot be achieved with single compounds or simpler mixtures.

Inventive Principle:
Principle #40Composite materials

2Temperature

If the nematic phase range is extended to low temperatures, then low temperature stability improves, but response time increases and switching becomes slower

Engineering Contradiction:
Improvenematic phase rangeVSAvoidresponse time
Core Design Contradiction:
TemperatureVSSpeed

Solution Approach 1:

The patent optimizes multiple physical parameters of the liquid crystal medium simultaneously. The compound composition is specifically designed to achieve: (1) broad nematic phase range from -40°C to +80°C or higher, (2) low rotational viscosity γ1 ≤ 80 mPa·s at 20°C for fast switching, (3) appropriate dielectric anisotropy Δε ≤ -3.0 at 1 kHz, and (4) suitable elastic constants ratio k33/k11 between 2.0 and 4.0. This multi-parameter optimization enables both low-temperature stability and fast response times ≤ 5 ms even at -30°C, resolving the trade-off between phase range extension and response speed.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If compounds are added to broaden nematic phase range, then low temperature performance improves, but other parameters like viscosity and dielectric properties deteriorate

Engineering Contradiction:
Improveparameter latitudeVSAvoidoverall performance stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent assigns specific functional roles to different compound classes within the mixture, creating local optimization of properties. Formula I compounds (14-24 wt%) are selected for their contribution to negative dielectric anisotropy, Formula II and III compounds (10-32 wt% and 12-20 wt%) are optimized for nematic phase stability and clearing point, Formula IV compounds (10-17 wt%) control rotational viscosity, Formula V compounds (34-40 wt%) provide high optical anisotropy, and Formula VI compounds (0-9 wt%) adjust melting and smectic-nematic transition points. This functional differentiation allows each compound class to optimize specific parameters without negatively impacting others, achieving overall performance stability with clearing points of 70-90°C, specific resistance ≥1×10^12 Ω·cm, and response times ≤5 ms.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The liquid crystal medium achieves superior performance with high specific resistance, low threshold voltage, broad nematic phase range, and fast switching times, enhancing the parameter latitude and stability, particularly suitable for 3D applications.

Implementation Method 1

Liquid crystal medium having a negative dielectric anisotropy Δε

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

a moderate or high birefringence may be required

Methodology Applied
Scientific EffectOptical anisotropy: Birefringence

Data Source

PatentEP2811004B1Liquid crystal medium and liquid crystal display
Publication Date: 2018.01.31 MERCK PATENT GMBH
  • EP2811004B1 patent drawing
  • EP2811004B1 patent drawing
  • EP2811004B1 patent drawing

AI summary

The present invention relates to a liquid crystal panel, a liquid crystal display device and to a liquid crystal medium having a negative dielectric anisotropy Δε.