Liquid-Crystal Medium for Fast Response and Low Image Sticking

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Solution Overview

Problem

Current liquid-crystal display technologies face challenges in achieving high specific resistance, short response times, and low threshold voltage while maintaining low-temperature stability and preventing image sticking, especially in VA and IPS displays used for monitors and televisions.

Innovation Solution

The use of polar compounds with a specific formula, which improves rotational viscosities and the ratio of rotational viscosity to elastic constants, resulting in liquid-crystal mixtures with short response times, broad nematic phase ranges, and good low-temperature behavior.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid-crystal mixtures are used in VA and IPS displays, then the displays can achieve basic electro-optical performance, but the response times are too long and image sticking occurs

Engineering Contradiction:
Improveimage sticking preventionVSAvoidresponse time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent changes the chemical composition parameters of the liquid-crystal mixture by introducing compounds with specific molecular structures (cyclohexylbenzene, phenylcyclohexane, and terphenyl compounds with particular substituent patterns). This compositional parameter change results in optimized physical parameters including reduced rotational viscosity and improved elastic constants, thereby achieving faster response times and preventing image sticking while maintaining electro-optical performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid-crystal mixture comprising multiple carefully selected compounds in specific proportions. The mixture combines cyclohexylbenzene compounds (20-60 wt%), phenylcyclohexane compounds (10-40 wt%), and terphenyl compounds (10-30 wt%), along with other auxiliary compounds. This composite formulation synergistically improves reliability by preventing image sticking while reducing response time, overcoming the limitations of conventional single-component or simpler mixture systems

Inventive Principle:
Principle #40Composite materials

2Loss of time

If liquid-crystal mixtures with fast response times are developed, then response time improves, but low-temperature stability and phase range may deteriorate

Engineering Contradiction:
Improveresponse timeVSAvoidlow-temperature stability
Core Design Contradiction:
Loss of timeVSStability of the object's composition

Solution Approach 1:

The patent optimizes the molecular structure parameters of the liquid-crystal compounds to achieve a balance between response time and thermal stability. By selecting compounds with specific structural features (rigid core structures combined with flexible alkyl chains) and controlling their proportions, the mixture achieves reduced rotational viscosity for fast response while maintaining appropriate melting points and phase ranges for low-temperature stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by assigning different functional roles to different compounds in the mixture. The cyclohexylbenzene compounds primarily provide fast response characteristics, the phenylcyclohexane compounds contribute to low-temperature stability and broad phase range, and the terphenyl compounds enhance electro-optical performance. This functional differentiation allows each component to optimize specific properties without compromising overall system performance

Inventive Principle:
Principle #3Local quality

3Reliability

If liquid-crystal mixtures with high specific resistance are used, then reliability improves, but threshold voltage and response time characteristics may worsen

Engineering Contradiction:
Improvespecific resistanceVSAvoidresponse time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent changes the electrical parameters of the liquid-crystal mixture by incorporating compounds with specific molecular structures that simultaneously provide high specific resistance and favorable electro-optical characteristics. The selected compounds have molecular structures that reduce ion content and improve dielectric properties, achieving high specific resistance (improved reliability) while maintaining appropriate threshold voltage and response time through optimized dielectric anisotropy and viscosity parameters

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described liquid-crystal mixtures exhibit improved response times, low rotational viscosities, and high elastic constants, enabling the production of displays with enhanced reliability and reduced image sticking, suitable for various display technologies including VA, IPS, and FFS.

Implementation Method 1

The invention relates to a liquid-crystalline medium, in particular based on a mixture of polar compounds, which comprises at least one compound of the formula I... for electro-optical displays having active-matrix addressing based on the ECB effect and for IPS (in-plane switching) displays or FFS (fringe field switching) displays

Methodology Applied
Scientific EffectElectro-optical effect: Electro-Optic Effects

Implementation Method 2

The principle of electrically controlled birefringence, the ECB effect or also DAP (deformation of aligned phases) effect, was described for the first time in 1971

Methodology Applied
Scientific EffectECB effect (electrically controlled birefringence):

Implementation Method 3

values for the dielectric anisotropy of Δ∈≤−0.5 in order to be suitable for use in high-information display elements based on the ECB effect

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 4

high values for the optical anisotropy Δn... The principle of electrically controlled birefringence, the ECB effect

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentUS11441073B2Liquid-crystalline medium
Publication Date: 2022.09.13 MERCK PATENT GMBH
  • US11441073B2 patent drawing
  • US11441073B2 patent drawing
  • US11441073B2 patent drawing

AI summary

The invention relates to a liquid-crystalline medium which comprises at least one compound of the formula I,wherein the radicals R11, L1, L2, n and A are as defined herein, and to the use thereof for an active-matrix display, in particular based on the VA, PSA, PS-VA, PA-VA, PALC, FFS, PS-FFS, IPS or PS-IPS effect.