Liquid-Crystal Medium for Fast Response and UV Stability

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Solution Overview

Problem

Existing liquid-crystal displays face challenges with high response times, low specific resistance, and instability under UV exposure and heat, particularly in mobile applications, where they require low addressing voltages and broad temperature stability while maintaining high voltage holding ratio and low rotational viscosity.

Innovation Solution

A liquid-crystal medium comprising a mixture of compounds of specific formulas, including at least one compound of formula I and one or more compounds of formula II, which provides a broad nematic phase range, high negative dielectric anisotropy, and low rotational viscosity, achieving stability and low threshold voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid-crystal compounds are used, then the display can operate, but the response time is too long

Engineering Contradiction:
Improveresponse timeVSAvoidstability under UV exposure and heat
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent uses composite liquid-crystal mixtures containing specific compounds (cyclohexane derivatives, phenyl cyclopropane carboxylic acid derivatives, and their deuterated analogs) to achieve both fast response times and high stability. The combination of different molecular structures with specific properties (low viscosity, high dielectric anisotropy) resolves the contradiction between speed and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies molecular parameters by introducing deuterated analogs and specific functional groups that reduce rotational viscosity while maintaining thermal stability. The compounds are designed with specific molecular weights, shapes, and intermolecular interaction characteristics to optimize both response time and stability under UV and heat exposure.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If liquid-crystal media with high specific resistance are used, then voltage holding ratio is good, but response time increases

Engineering Contradiction:
Improvevoltage holding ratioVSAvoidresponse time
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent achieves the balance by carefully controlling the dielectric anisotropy and rotational viscosity parameters of the liquid-crystal compounds. The specific molecular structures are designed to provide high dielectric anisotropy (for fast response) while maintaining appropriate ionic conductivity (for good voltage holding ratio). The deuterated compounds and specific functional groups optimize these electrical parameters simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Speed

If liquid-crystal compounds with low rotational viscosity are used, then response time is short, but stability under heat and UV exposure deteriorates

Engineering Contradiction:
Improveresponse timeVSAvoidstability under heat and UV exposure
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The patent creates a composite mixture where compounds with low rotational viscosity (for fast response) are combined with thermally stable and UV-resistant molecular structures. The specific combination of cyclohexane derivatives, phenyl cyclopropane carboxylic acid derivatives, and their deuterated analogs ensures that the mixture maintains both fast response characteristics and high stability under heat and UV exposure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent converts the potential harm of low-viscosity compounds (poor stability) into a benefit by using deuterated analogs and specific stable molecular cores that inherently resist degradation. The molecular structures are designed to be inherently stable while maintaining low viscosity, turning what would normally be a compromise into a dual benefit.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Use of energy by moving object

If liquid-crystal displays are designed for mobile applications, then low addressing voltage is required, but this conflicts with achieving short response time and high stability

Engineering Contradiction:
Improveaddressing voltageVSAvoidresponse time
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent optimizes the dielectric anisotropy and viscosity parameters to achieve low threshold voltage while maintaining fast response. The specific molecular structures provide high dielectric anisotropy (reducing required voltage) combined with low rotational viscosity (maintaining fast response). The deuterated compounds and functional groups are selected to optimize this voltage-speed-stability triangle for mobile applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in liquid-crystal displays with short response times, high specific resistance, and excellent stability under UV exposure and heat, suitable for various applications including mobile devices, with improved voltage holding ratio and low rotational viscosity.

Implementation Method 1

The principle of electrically controlled birefringence, the ECB effect or DAP (deformation of aligned phases) effect, was described for the first time in 1971

Methodology Applied
Scientific EffectElectrically controlled birefringence (ECB effect): Birefringence

Implementation Method 2

The principle of electrically controlled birefringence, the ECB effect or DAP (deformation of aligned phases) effect, was described for the first time in 1971

Methodology Applied
Scientific EffectDeformation of aligned phases (DAP effect): Deformation

Implementation Method 3

values for the dielectric anisotropy Δε of −0.5 in order to be suitable for use for high-information display elements based on the ECB effect

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Data Source

PatentUS10907100B2Compounds and liquid-crystalline medium
Publication Date: 2021.02.02 MERCK PATENT GMBH
  • US10907100B2 patent drawing
  • US10907100B2 patent drawing
  • US10907100B2 patent drawing

AI summary

Compounds of formula I, and liquid-crystalline media, preferably having a nematic phase and negative dielectric anisotropy, comprising:a) one or more compounds of formula Iand one or more other compounds selected from:b) one or more compounds of formula IIand/orc) one or more compounds selected from compounds of formulae III-1 to III-4 and BUse thereof in electro-optical displays, particularly in active-matrix displays based on the VA, ECB, PALC, FFS or IPS effect and use of compounds of formula I for stabilisation of liquid-crystalline media which comprise one or more compounds of formula II and/or one or more compounds selected from compounds of formulae III-1 to III-4 and B.