Liquid Crystal Medium for Fast Switching and Low Voltage ECB Displays

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Solution Overview

Problem

Liquid crystal displays using the ECB effect with negative dielectric anisotropy liquid crystals face challenges in achieving short switching times, high voltage holding ratio, and low operational voltages, leading to high current consumption and insufficient contrast and viewing angle stability, particularly in mobile and TV applications.

Innovation Solution

A liquid-crystalline medium based on a mixture of polar compounds, including specific formula I compounds, is used, which provides a broad nematic phase range, high negative dielectric anisotropy, and low rotational viscosity, enabling efficient electro-optical performance with improved switching times and resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If liquid crystal media with negative dielectric anisotropy are used for ECB displays, then the operational voltage can be kept low, but the switching time becomes too long

Engineering Contradiction:
Improveoperational voltageVSAvoidswitching time
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent changes the physical and chemical parameters of the liquid crystal compounds by introducing specific molecular structures (cyclohexenylene units with fluorinated phenyl groups) that simultaneously optimize dielectric anisotropy, rotational viscosity, and switching response. This resolves the contradiction by finding compound formulations that achieve both low operational voltage and fast switching time through parameter optimization rather than compromise

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite liquid crystal media containing multiple compounds with different properties (cyclohexenylene derivatives, fluorinated phenyl compounds, and other mesogenic substances) to achieve synergistic effects. The composite formulation combines compounds with high negative dielectric anisotropy for low voltage operation with compounds having low rotational viscosity for fast switching, resolving the technical contradiction

Inventive Principle:
Principle #40Composite materials

2Reliability

If compounds with negative dielectric anisotropy are used predominantly, then the voltage holding ratio improves, but the switching time increases

Engineering Contradiction:
Improvevoltage holding ratioVSAvoidswitching time
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent optimizes the molecular parameters of the liquid crystal compounds by incorporating cyclohexenylene units with specific substituent patterns that enhance both dielectric anisotropy (for voltage holding) and reduce rotational viscosity (for switching speed). The fluorinated phenyl groups specifically tune the dielectric properties while the overall molecular structure controls viscosity, resolving the contradiction between reliability and speed

Inventive Principle:
Principle #35Parameter changes

3Speed

If the rotational viscosity is reduced to improve switching time, then the switching time becomes short, but the voltage holding ratio decreases

Engineering Contradiction:
Improveswitching timeVSAvoidvoltage holding ratio
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent employs composite liquid crystal formulations where different compounds perform complementary functions: some compounds (with specific cyclohexenylene structures) provide low rotational viscosity for fast switching, while other compounds (with fluorinated phenyl groups) maintain high dielectric anisotropy for voltage holding. The composite approach allows simultaneous optimization of both properties without compromise

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves short switching times, high voltage holding ratio, and low operational voltages, enhancing the performance and stability of liquid crystal displays, particularly in mobile and TV applications, while maintaining low rotational viscosity and broad nematic phase ranges.

Implementation Method 1

Liquid crystal displays that use the ECB (E electrically C controlled B irefringence) effect with dielectrically negative liquid crystals

Methodology Applied
Scientific EffectElectrically controlled birefringence (ECB) effect: Birefringence

Implementation Method 2

liquid crystalline media with negative dielectric anisotropy (Δε)

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 3

the liquid crystals are used as dielectrics whose optical properties change reversibly when an electrical voltage is applied

Methodology Applied
Scientific EffectElectro-optical effect: Electro-Optic Effects

Data Source

PatentEP2199362B1Liquid crystalline medium
Publication Date: 2012.08.29 MERCK PATENT GMBH
  • EP2199362B1 patent drawing
  • EP2199362B1 patent drawing
  • EP2199362B1 patent drawing

AI summary

Liquid crystalline medium (A) comprises a mixture of dielectric negative, polar cyclohexane compounds (I). Liquid crystalline medium (A) comprises a mixture of dielectric negative, polar cyclohexane compounds of formula (I). R 11>, R 12> : H, up to 15C-unsubstituted alkyl or -alkenyl (where one or more CH 2-groups are substituted by -O-, -S-, -cyclobutane-1,4-yl-, -C?=C-, -CF 2-O-, -O-CF 2-, -CO-O- or -O-CO- (where O atoms are not directly connected)); ring A 11>-ring A 14> : 2,3-difluoro-benzene-1,4-yl, tetrahydro-pyran-2,5-yl moieties (all preferred), 3-chloro-2-fluoro-benzene-1,4-yl, 2-chloro-3-fluoro-benzene-1,4-yl, cyclohexene-1,4-yl moieties, cyclohexane-1,4-yl, 2-fluoro-cyclohexene-1,4-yl moieties, [1,3]dioxane-2,5-yl moieties, benzene-1,4-yl, 2-fluoro-benzene-1,4-yl moieties or 2,3-difluoro-benzene-1,4-yl; Z 11>-Z 13> : -CH 2-CH 2-, -CH=CH-, -C?=C-, -CH 2-O-, -O-CH 2-, -CO-O-, -O-CO-, -CF 2-O-, -O-CF 2-, -CF 2-CF 2- or a bond (preferred); and m, n : 0 or 1. An independent claim is included for an electro optical display comprising (A). [Image].