Liquid-Crystal Medium for High Transmission Low Voltage Displays

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Solution Overview

Problem

Current liquid-crystal displays using dielectrically negative liquid crystals have increased transmission but require higher operation voltages, and existing media fail to meet requirements for chemical resistance, temperature range, and low viscosity, leading to issues with contrast, response time, and stability, especially in mobile applications.

Innovation Solution

A liquid-crystal medium comprising compounds of specific formulas, such as those in formulas I, II, III, IV, and V, which provide high dielectric anisotropy, low rotational viscosity, and broad nematic phase ranges, ensuring high transmission, short response times, and stability across extreme temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If dielectrically negative liquid crystals are used to increase transmission, then transmission is improved, but operation voltage increases

Engineering Contradiction:
ImprovetransmissionVSAvoidoperation voltage
Core Design Contradiction:
Illumination intensityVSUse of energy by stationary object

Solution Approach 1:

The patent changes the dielectric anisotropy parameter from negative to positive values, while simultaneously optimizing other parameters like dielectric constant and viscosity to achieve both high transmission and low operating voltage. Specific compounds with positive dielectric anisotropy of +0.5 to +3.0 are used to resolve this contradiction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite liquid crystal mixtures containing multiple compounds with different properties (dielectrically positive compounds, dielectrically negative compounds, and dielectrically neutral compounds) to achieve a balanced performance that provides both high transmission and low operating voltage, neither of which can be achieved with single-component systems.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If existing liquid crystalline media are used, then manufacturing is simplified, but chemical resistance and temperature stability are insufficient

Engineering Contradiction:
Improvemedia preparationVSAvoidchemical resistance and temperature stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses composite liquid crystal mixtures containing specific compounds (formulas I-V) with proven stability properties, combined in optimized ratios to achieve both ease of manufacture and superior reliability in terms of chemical resistance and temperature stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent assigns specific functional roles to different compounds in the mixture: some compounds provide chemical resistance, others provide temperature stability, and others provide dielectric properties. This local optimization of properties within the composite system resolves the contradiction between manufacturing simplicity and reliability.

Inventive Principle:
Principle #3Local quality

3Power

If liquid crystalline media with large dielectric constants are used, then dielectric ratio is improved, but response time increases due to viscosity

Engineering Contradiction:
Improvedielectric ratioVSAvoidresponse time
Core Design Contradiction:
PowerVSSpeed

Solution Approach 1:

The patent simultaneously optimizes multiple parameters: dielectric constant (ε⊥), dielectric anisotropy (Δε), and rotational viscosity (γ1). By selecting compounds with specific molecular structures and properties, the patent achieves high dielectric ratio while maintaining low viscosity for fast response times.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses different compounds for different functions: some compounds contribute primarily to dielectric properties while others contribute to viscosity control. This functional differentiation within the mixture allows simultaneous optimization of both power efficiency and response speed.

Inventive Principle:
Principle #3Local quality

4Manufacturing precision

If single compounds are used to simplify composition, then manufacturing precision is improved, but no single compound meets all requirements for chemical resistance, temperature range, and viscosity

Engineering Contradiction:
Improvecomposition consistencyVSAvoidchemical resistance, temperature range, and viscosity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent employs composite liquid crystal mixtures where each component contributes specific properties. The combination of multiple compounds (formulas I-V) in defined ratios achieves a balance of chemical resistance, temperature range, and viscosity that no single compound can provide alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent divides the functional requirements into separate components: one compound may provide chemical resistance, another provides temperature stability, and another provides optimal viscosity. This segmentation of functions across multiple compounds resolves the contradiction while maintaining manufacturing precision through standardized mixture formulations.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid-crystal medium achieves low threshold voltage, rapid response times, and high stability, enabling efficient energy use and reliable performance in diverse temperature conditions, particularly suitable for mobile and TV applications.

Implementation Method 1

The liquid-crystal media according to the invention have a positive dielectric anisotropy and comprise compounds having at the same time large dielectric constants parallel and perpendicular to the molecular director

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

IPS and FFS displays using dielectrically positive liquid crystals are well known in the field and have been widely adopted

Methodology Applied
Scientific EffectIn-plane switching effect: Electro-Optic Effects

Implementation Method 3

particularly the FFS (fringe field switching) effect using dielectrically positive liquid crystals

Methodology Applied
Scientific EffectFringe field switching effect: Electro-Optic Effects

Implementation Method 4

The media are distinguished by a particularly high transmission and reduced response time in respective displays, which is brought about by their unique combination of physical properties

Methodology Applied
Scientific EffectBirefringence: Birefringence

Data Source

PatentEP3434751B1Liquid-crystalline medium and liquid-crystal display comprising the same
Publication Date: 2021.06.16 MERCK PATENT GMBH
  • EP3434751B1 patent drawing
  • EP3434751B1 patent drawing
  • EP3434751B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium, which comprises one or more compounds of formula I in which denotes or and the other the parameters have the meanings given in the text, to the use thereof in an electro-optical display, particularly in an active-matrix display based on the IPS or FFS effect, to displays of this type which contain a liquid-crystalline medium of this type, and to the use of the compounds of formula I for the improvement of the transmission and/or response times of a liquid-crystalline medium which comprises one or more additional mesogenic compounds.