Liquid Crystal Medium for Fast Switching and UV Stability

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Solution Overview

Problem

Existing liquid crystal mixtures for electro-optical displays, particularly those based on the ECB, IPS, and FFS effects, face challenges such as insufficient specific resistance, high switching times, and poor grayscale generation, along with issues like image sticking and decreased voltage holding capacity under UV exposure and elevated temperatures.

Innovation Solution

A liquid-crystalline medium containing compounds of formulas I-1 and/or I-2, combined with specific additives, which provides improved stability, negative dielectric anisotropy, and low rotational viscosity, enabling short switching times and high voltage holding ratios, even at extreme temperatures and under UV exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid crystal mixtures are used for ECB, IPS, and FFS displays, then the displays can operate with basic performance, but the switching times are long and grayscale generation is poor

Engineering Contradiction:
Improveswitching timesVSAvoidgrayscale generation performance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of the liquid crystal mixture by introducing compounds with specific molecular structures (formulas I-1 and I-2) that have negative dielectric anisotropy and low rotational viscosity. This fundamentally alters the electro-optical response characteristics, enabling fast switching times while maintaining good grayscale generation through optimized elastic constant ratios (K3/K1).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite liquid crystal mixture combining multiple compounds with different functions: the core compounds (I-1 and I-2) provide negative dielectric anisotropy and fast response, while additional compounds from formulas IIA, IIB, and IIC contribute to stability, temperature range, and optical properties. This composite approach achieves both fast switching and reliable grayscale generation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing liquid crystal mixtures are used, then the displays can function under normal conditions, but they exhibit image sticking and decreased voltage holding capacity under UV exposure and elevated temperatures

Engineering Contradiction:
Improvevoltage holding capacityVSAvoidUV exposure and temperature effects
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent incorporates stabilizing compounds and additives in the liquid crystal mixture that preemptively protect against UV degradation and temperature-induced damage. These compounds absorb or neutralize harmful effects before they can cause image sticking or voltage holding capacity loss, ensuring reliable operation under extreme conditions.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The invention modifies the chemical composition parameters by selecting compounds with high thermal stability and UV resistance. The specific molecular structures in formulas I-1, I-2, IIA, IIB, and IIC are chosen to maintain molecular integrity and electro-optical properties under elevated temperatures and UV exposure, preventing degradation and maintaining voltage holding capacity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If standard liquid crystal mixtures are used, then the displays can operate with acceptable performance, but the specific resistance is insufficient leading to poor display quality

Engineering Contradiction:
Improvespecific resistanceVSAvoiddisplay quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the electrical parameters of the liquid crystal mixture by incorporating compounds with optimized molecular structures that increase specific resistance. The compounds in formulas I-1, I-2, and the additional compounds are selected to minimize ionic conductivity and maximize resistive properties, achieving high specific resistance for superior display quality and reduced image sticking.

Inventive Principle:
Principle #35Parameter changes

4Speed

If conventional liquid crystal mixtures are used, then the displays can operate with basic functionality, but the rotational viscosity is high resulting in slow response times

Engineering Contradiction:
Improveresponse timesVSAvoidrotational viscosity
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The invention fundamentally changes the rheological parameters by introducing compounds with low rotational viscosity. The molecular structures in formulas I-1 and I-2 are designed to reduce intermolecular friction and facilitate rapid reorientation under electric fields, achieving fast response times while maintaining composition stability through the synergistic effect of multiple compounds.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid-crystalline medium achieves stable performance with broad nematic phase ranges, high voltage holding ratios, and low rotational viscosities, addressing the limitations of previous mixtures by ensuring reliable operation across a wide temperature range and improved UV resistance.

Implementation Method 1

Electro-optical displays with active matrix addressing based on the ECB effect

Methodology Applied
Scientific EffectECB effect (electrically controlled birefringence): Birefringence

Implementation Method 2

for IPS displays (In plane switching)

Methodology Applied
Scientific EffectIPS effect (In plane switching):

Implementation Method 3

or FFS displays (Fringe Field Switching)

Methodology Applied
Scientific EffectFFS effect (Fringe Field Switching):

Implementation Method 4

values for the dielectric anisotropy of Δε ≤ -0.5

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Data Source

PatentEP3149110B1Liquid crystal medium
Publication Date: 2019.12.11 MERCK PATENT GMBH
  • EP3149110B1 patent drawing
  • EP3149110B1 patent drawing
  • EP3149110B1 patent drawing

AI summary

The invention relates to a liquid crystal medium, which contains the compound of formula I-1 and/or the compound of formula I-2 and additionally contains one or more compounds selected from the group of the compounds of formulas IIA, IIB, and IIC, wherein R2A, R2B, R2C, L1-4, Z2, Z2', p, q, and v have the meanings specified in claim 1. The invention further relates to the use of said liquid crystal medium for an active-matrix display, in particular based on the VA, PSA, PA-VA, PS-VA, PALC, IPS, PS-IPS, FFS, UB-FFS, or PS-FFS effect.