Liquid Crystal Medium for High Voltage Holding Ratio

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Solution Overview

Problem

Current liquid crystal displays face challenges with viewing-angle dependence, contrast, and reliability, particularly in TN and VA modes, and there is a need for materials with improved voltage holding ratio (VHR) and reduced mechanical sensitivity.

Innovation Solution

A liquid crystal medium comprising specific compounds with formulae I, IIA, IIB, IIC, and IID, along with mixtures X-1 and X-2, which enhance the VHR and reliability by optimizing the alignment and stability of LC molecules, thereby improving display performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If TN mode is used, then the display structure is simple, but the viewing-angle dependence of contrast is strong

Engineering Contradiction:
Improvedisplay structureVSAvoidviewing angle
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent uses a composite liquid crystal medium comprising multiple compounds (cyclic carboxylic acid compounds, cyclic carbonate compounds, and specific liquid crystal compounds with formulas I, II, III) to achieve both simple TN mode structure and improved viewing angle characteristics. The composite formulation allows optimization of multiple parameters simultaneously.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If VA mode is used, then the viewing angle is broader, but the voltage holding ratio decreases after UV light load

Engineering Contradiction:
Improveviewing angleVSAvoidvoltage holding ratio
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the liquid crystal medium by incorporating specific compounds (cyclic carboxylic acid compounds like 4'-cyclohexyl-4-biphenylcarboxylic acid and its derivatives, cyclic carbonate compounds) to improve voltage holding ratio while maintaining broad viewing angle characteristics of VA mode.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite liquid crystal formulation combining cyclic carboxylic acid compounds, cyclic carbonate compounds, and liquid crystal compounds with specific molecular structures (formulas I, II, III) to achieve both broad viewing angle and high voltage holding ratio after UV light exposure.

Inventive Principle:
Principle #40Composite materials

3Reliability

If the LC medium composition is optimized for VHR, then the reliability improves, but the manufacturing complexity increases

Engineering Contradiction:
Improvevoltage holding ratioVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes specific compositional parameters (ratios of cyclic carboxylic acid compounds, cyclic carbonate compounds, and liquid crystal compounds with specific formulas) to achieve high voltage holding ratio while maintaining manufacturability through well-defined composition ranges.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid crystal medium significantly improves the voltage holding ratio, especially after UV light load, and enhances the reliability and mechanical stability of LC displays, addressing the limitations of existing materials.

Implementation Method 1

The LC medium usually has a negative dielectric anisotropy... On application of an electrical voltage to the two electrodes, a realignment of the LC molecules parallel to the electrode surfaces takes place

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

OCB ('optically compensated bend') displays are known which are based on a birefringence effect

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 3

an alignment layer, usually of polyimide, which provides planar alignment to the molecules of the LC medium

Methodology Applied
Scientific EffectSurface alignment: Adsorption

Data Source

PatentUS11920074B2Liquid crystal medium
Publication Date: 2024.03.05 MERCK PATENT GMBH
  • US11920074B2 patent drawing
  • US11920074B2 patent drawing
  • US11920074B2 patent drawing

AI summary

The present invention relates to a liquid crystal (LC) medium comprising a compound of formula Iandone or more compounds selected from the group of compounds of the formulae IIA, IIB, IIC and IID,as defined in claim 1, and to the use of the LC medium for optical, electro-optical and electronic purposes, in particular in LC displays, especially in IPS, FFS, VA or PS-VA displays.