Liquid Crystal Functionalized Polymer Thermal Interface Materials

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Solution Overview

Problem

Current thermal interface materials struggle to enhance thermal conductivity without increasing filler loading, which can compromise the mechanical and electrical properties of electronic components, leading to reduced performance and reliability due to excessive heat generation.

Innovation Solution

The development of polymer matrices functionalized with liquid crystals, where liquid crystalline units are grafted onto the polymer matrix, enhancing thermal conductivity without increasing filler loading, while maintaining mechanical and electrical insulation properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If filler loading is increased to enhance thermal conductivity, then thermal conductivity is improved, but mechanical and electrical properties are compromised

Engineering Contradiction:
Improvethermal conductivityVSAvoidmechanical and electrical properties
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The invention changes the chemical and physical parameters of the polymer matrix by functionalizing it with liquid crystals. This modification alters the thermal conductivity parameter of the matrix itself, allowing heat dissipation improvement without adding traditional fillers that would compromise mechanical and electrical properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure at the molecular level by grafting liquid crystalline units onto the polymer matrix chains. This forms a hybrid material system where the liquid crystal-functionalized polymer provides enhanced thermal conductivity while maintaining the base polymer's mechanical integrity and electrical insulation properties.

Inventive Principle:
Principle #40Composite materials

2Temperature

If thermal interface material is used to fill gaps between electronic component and heat sink, then thermal transfer efficiency is improved, but the material complexity increases

Engineering Contradiction:
Improvethermal transfer efficiencyVSAvoidmaterial complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The polymer matrix functionalized with liquid crystals serves multiple functions simultaneously: it acts as a thermal interface material for heat dissipation, maintains electrical insulation properties, and provides mechanical compliance for gap filling. This multi-functionality eliminates the need for separate specialized components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The liquid crystal-functionalized polymer matrix inherently provides the necessary thermal conduction capability through its molecular structure, eliminating the need for additional filler materials or complex multi-layer constructions. The material serves its own thermal management function through its intrinsic properties.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a thermally conductive composite with improved thermal conductivity, retaining desired mechanical and electrical properties, and allowing for the creation of soft, conformable thermal interface materials with tunable electrical conductivity.

Implementation Method 1

enhancing thermal conductivity without increasing filler loading

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

polymer matrices functionalized with liquid crystals where liquid crystalline units are grafted onto the polymer matrix

Methodology Applied
Scientific EffectLiquid crystal phase behavior: Liquid Crystals

Data Source

PatentUS9376606B2Polymer matrices functionalized with liquid crystals for enhanced thermal conductivity
Publication Date: 2016.06.28 LAIRD TECHNOLOGIES INC
  • US9376606B2 patent drawing
  • US9376606B2 patent drawing

AI summary

According to various aspects, exemplary embodiments are disclosed of thermally conductive composites that include a polymer matrix functionalized with liquid crystals grafted onto the polymer matrix. Also disclosed are methods that generally include modifying liquid crystals and incorporating the modified liquid crystals into a polymer matrix such that the modified liquid crystals are grafted onto the polymer matrix.