Liquid Crystalline Medium for ECB Displays

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Solution Overview

Problem

Liquid crystal displays using the ECB effect with dielectrically negative liquid crystals face challenges in achieving short switching times, high voltage holding capacity, and stability against UV and temperature stress, leading to issues with contrast, viewing angle dependence, and service life.

Innovation Solution

A liquid-crystalline medium comprising a mixture of specific compounds, including at least one compound of formula I and one or more compounds from formulas II-1 to II-4, which provides a broad nematic phase range, high negative dielectric anisotropy, and low rotational viscosity, stabilizing the mixture against UV and temperature exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If liquid crystal mixtures are used with high negative dielectric anisotropy to achieve short switching times, then switching speed is improved, but voltage holding ratio deteriorates

Engineering Contradiction:
Improveswitching timeVSAvoidvoltage holding ratio
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully adjusting the composition ratios of multiple liquid crystal compounds (cyclohexylbenzene derivatives, terphenyl derivatives, toluene derivatives) to achieve an optimal balance between dielectric anisotropy and voltage holding ratio. The specific weight percentages of each compound are tuned to maintain both fast switching and high stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by creating a multi-component liquid crystal mixture where each compound contributes different properties. The combination of cyclohexylbenzene derivatives (for dielectric anisotropy), terphenyl derivatives (for clearing point and phase stability), and toluene derivatives (for viscosity control) produces a composite system that simultaneously achieves short switching times and high voltage holding ratio.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If liquid crystal mixtures are designed for high contrast and viewing angle performance, then image quality is improved, but switching time increases

Engineering Contradiction:
Improveimage qualityVSAvoidswitching time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies parameter changes by optimizing the birefringence (Δn) and dielectric anisotropy (Δε) parameters through compound selection and ratio adjustment. The mixture achieves Δn ≥ 0.10 and |Δε| ≥ 3.0, creating a balance where optical performance is maintained while switching speed is improved through low rotational viscosity compounds.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by assigning specific functional roles to different compound classes within the mixture. Cyclohexylbenzene derivatives provide dielectric anisotropy for fast response, terphenyl derivatives provide optical anisotropy for image quality, and toluene derivatives provide viscosity control. Each component optimizes a specific local property.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If liquid crystal displays operate at extreme temperatures, then environmental adaptability is improved, but stability against UV and temperature stress deteriorates

Engineering Contradiction:
Improvetemperature rangeVSAvoidstability against UV and temperature stress
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies parameter changes by adjusting the clearing point and phase stability parameters through compound selection. The mixture maintains a clearing point ≥ 70°C and broad nematic phase range, while the specific chemical structures of the compounds provide inherent stability against UV degradation and thermal stress.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of extreme temperature and UV exposure into a benefit by selecting compounds with inherent photostability and thermal stability. The aromatic structures and specific molecular configurations of the cyclohexylbenzene, terphenyl, and toluene derivatives resist degradation, turning environmental stress into a demonstration of robustness.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Use of energy by moving object

If liquid crystal mixtures use compounds with high dielectric anisotropy to reduce threshold voltage, then power consumption is reduced, but voltage holding ratio decreases

Engineering Contradiction:
Improvepower consumptionVSAvoidvoltage holding ratio
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent applies parameter changes by optimizing the dielectric anisotropy parameter to achieve |Δε| ≥ 3.0, which reduces threshold voltage and power consumption. Simultaneously, the composition ratios are adjusted and stabilizing compounds are added to maintain high voltage holding ratio, creating a balanced energy-efficient system.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining compounds with high dielectric anisotropy (for low power) with compounds that provide structural stability and high voltage holding ratio. The multi-component system distributes functions: some compounds enable low threshold voltage while others ensure long-term stability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves short switching times, high voltage holding ratio, and stability at extreme temperatures, improving the performance and longevity of liquid crystal displays, particularly in mobile and TV applications.

Implementation Method 1

high negative dielectric anisotropy

Methodology Applied
Scientific EffectDielectric anisotropy: Anisotropy

Implementation Method 2

the ECB effect with dielectrically negative liquid crystals in a homeotropic output orientation

Methodology Applied
Scientific EffectElectric field effect on liquid crystals: Electric Field

Implementation Method 3

electrically controlled birefringence, the ECB effect

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 4

stability against UV and temperature stress

Methodology Applied
Scientific EffectPhotostability: Absorption (EM radiation)

Implementation Method 5

stability at extreme temperatures

Methodology Applied
Scientific EffectThermal stability: Thermal Radiation

Data Source

PatentEP3093328B1Liquid crystalline medium
Publication Date: 2018.06.13 MERCK PATENT GMBH
  • EP3093328B1 patent drawing
  • EP3093328B1 patent drawing
  • EP3093328B1 patent drawing

AI summary

The invention relates to compounds of formula I, as well as a liquid crystalline medium, preferably with a nematic phase and a negative dielectric anisotropy, which contains a) one or more compounds of formula I and b) one or more compounds of formulas II-1 to II-4, wherein the parameters have the respective meanings specified in claim 1, and its use in an electro-optical display, particularly in an active matrix display based on the VA, ECB, PALC, FFS or IPS effect.