Liquid-Crystalline Medium for High Resistance Displays

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Solution Overview

Problem

Existing liquid-crystal mixtures for matrix liquid-crystal displays (MLC) and other electro-optical applications face challenges such as insufficient specific resistance, high threshold voltages, limited temperature stability, and poor UV resistance, which affect display performance and lifespan, particularly at low temperatures and under UV exposure.

Innovation Solution

A liquid-crystalline medium comprising specific compounds of formulas I and E, which provide high specific resistance, low rotational viscosities, broad nematic phase ranges, and improved thermal and UV stability, enabling efficient operation at low temperatures and reduced threshold voltages.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid-crystal mixtures are used in MLC displays, then the display can operate, but the specific resistance is insufficient leading to poor contrast and after-image elimination problems

Engineering Contradiction:
Improvespecific resistanceVSAvoiddisplay performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the chemical composition parameters of the liquid-crystal mixture by incorporating specific compounds (formula I with c=0, Z1-Z4 definitions and formula E compounds) to achieve high specific resistance values while maintaining other necessary display performance characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite liquid-crystal materials combining multiple components including compounds of formula I and formula E in specific proportions to achieve the desired high specific resistance and broad nematic phase range simultaneously

Inventive Principle:
Principle #40Composite materials

2Reliability

If liquid-crystal mixtures with high specific resistance are used, then contrast improves, but threshold voltage increases

Engineering Contradiction:
Improvespecific resistanceVSAvoidthreshold voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent adjusts the chemical composition parameters by selecting specific compounds with optimized molecular structures (formula I with specific R1-R6, Z1-Z4 groups and formula E compounds) to achieve high specific resistance while controlling threshold voltage through the inherent properties of the selected materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces specific functional groups and molecular structures in localized regions of the liquid-crystal molecules to achieve high specific resistance in the bulk material while maintaining low threshold voltage through the specific molecular design of compounds I and E

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If liquid-crystal mixtures are used with broad nematic phase range, then temperature stability improves, but viscosity increases reducing response time

Engineering Contradiction:
Improvenematic phase rangeVSAvoidresponse time
Core Design Contradiction:
Stability of the object's compositionVSSpeed

Solution Approach 1:

The patent modifies the molecular structure parameters of the liquid-crystal compounds (formula I and E) to achieve broad nematic phase range while controlling viscosity through the specific choice of substituents and molecular configurations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention combines multiple liquid-crystal compounds with different molecular structures and phase behaviors to achieve a composite mixture with broad nematic phase range and optimized viscosity for fast response times

Inventive Principle:
Principle #40Composite materials

4Reliability

If liquid-crystal mixtures are used in MLC displays, then display operation is enabled, but UV resistance is poor leading to degradation over time

Engineering Contradiction:
ImproveUV resistanceVSAvoidservice life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent modifies the chemical composition by incorporating UV-stable liquid-crystal compounds (formula I and E with specific molecular structures) that resist degradation from UV radiation, thereby extending the service life of the display

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses the inherent stability of specific molecular structures (formula I and E compounds) to convert the harmful effect of UV radiation into a non-degrading state, where the liquid-crystal material resists UV-induced degradation and maintains performance over time

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid-crystalline medium achieves significant improvements in specific resistance, thermal stability, and UV resistance, allowing for high-performance MLC displays with extended operational temperature ranges and reduced voltage requirements, enhancing display durability and efficiency.

Implementation Method 1

They should furthermore have a suitable mesophase, for example a nematic or cholesteric mesophase for the above-mentioned cells, at the usual operating temperatures

Methodology Applied
Scientific EffectNematic phase: Liquid Crystals

Implementation Method 2

Liquid crystals are used principally as dielectrics in display devices, since the optical properties of such substances can be modified by an applied voltage

Methodology Applied
Scientific EffectDielectric: Dielectric

Implementation Method 3

The liquid-crystal materials should have low viscosity and produce short addressing times

Methodology Applied
Scientific EffectRotational viscosity: Viscometer

Data Source

PatentEP2457975B1Liquid-crystalline mixtures
Publication Date: 2014.06.25 MERCK PATENT GMBH
  • EP2457975B1 patent drawing
  • EP2457975B1 patent drawing
  • EP2457975B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium containing at least one compound of the formula I and at least one compound of the formula E in which R1, RE, A1, A2, A3, X1, XE, L1, L2, L3, L4, Z1, Z2, Z3, a, b and c are as defined in Claim 1, and to their use in electro-optical displays.