Liquid-Crystalline Medium for Fast Response and Low-Temperature Stability

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Solution Overview

Problem

Current liquid-crystal display technologies face challenges in achieving fast response times, high reliability, and low-temperature stability while maintaining acceptable contrast and image quality, especially in ECB and IPS/FFS displays, due to limitations in dielectric anisotropy, rotational viscosity, and long-term stability of existing liquid-crystal mixtures.

Innovation Solution

A liquid-crystalline medium comprising specific compounds of formulas I1, I2, and EY, which reduce rotational viscosity and enhance dielectric anisotropy, allowing for the creation of mixtures with short response times, broad nematic phase ranges, and high low-temperature stability, suitable for VA, IPS, and FFS displays.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid-crystal mixtures are used in ECB and IPS/FFS displays, then the displays can achieve acceptable contrast and image quality, but the response times are slow and image sticking issues occur over long operating periods

Engineering Contradiction:
Improvelong-term stabilityVSAvoidresponse time
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent applies parameter changes by modifying the dielectric anisotropy (Δε) to be significantly negative (≤−0.5) and adjusting the rotational viscosity (γ1) to ≤150 mPa·s through specific compound formulations. This resolves the contradiction by changing the physical parameters of the liquid-crystal medium to achieve both fast response times and long-term stability in ECB and IPS/FFS displays

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by formulating liquid-crystal mixtures containing specific compounds (compounds of formulae I1 and I2 in amounts of 3-50 wt%, compounds of formulae IA and/or IB in amounts of 20-70 wt%, and compounds of formulae IIC in amounts of 1-20 wt%). This composite approach enables simultaneous optimization of response time, contrast ratio, and long-term reliability

Inventive Principle:
Principle #40Composite materials

2Speed

If liquid-crystal mixtures with significantly negative dielectric anisotropy are used to reduce rotational viscosity and improve response times, then fast response is achieved, but long-term stability and reliability deteriorate

Engineering Contradiction:
Improveresponse timeVSAvoidlong-term stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent simultaneously optimizes multiple parameters: dielectric anisotropy (Δε≤−0.5), rotational viscosity (γ1≤150 mPa·s), and elastic constants (K1, K3). By coordinating changes in these parameters through specific compound ratios, the patent achieves both fast response times and improved long-term stability, resolving the contradiction between speed and reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite liquid-crystal materials with a multi-component formulation where compounds of formulae I1 and I2 (providing negative dielectric anisotropy) are combined with compounds of formulae IA/IB (providing nematogeneity and stability) and IIC (adjusting physical properties). This composite structure enables simultaneous achievement of fast response and long-term reliability

Inventive Principle:
Principle #40Composite materials

3Temperature

If existing liquid-crystal compounds are used to achieve broad nematic phase ranges and low-temperature stability, then temperature performance is improved, but response times increase and dielectric anisotropy is insufficient

Engineering Contradiction:
Improvelow-temperature stabilityVSAvoidresponse time
Core Design Contradiction:
TemperatureVSSpeed

Solution Approach 1:

The patent changes the physical parameters of the liquid-crystal medium by selecting compounds with specific molecular structures and properties. The formulation achieves broad nematic phase ranges (−20°C to +80°C) while maintaining low rotational viscosity (γ1≤150 mPa·s) and significantly negative dielectric anisotropy (Δε≤−0.5), thereby improving both temperature stability and response time simultaneously

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed liquid-crystalline medium achieves significantly improved response times, reliability, and low-temperature stability, enabling the development of liquid-crystal displays with enhanced performance and reduced image sticking issues over long operating periods.

Implementation Method 1

The present invention relates to a liquid-crystalline medium (LC medium), to the use thereof for electro-optical purposes, in particular for electro-optical displays having active-matrix addressing based on the ECB (electrically controlled birefringence) effect

Methodology Applied
Scientific EffectElectrically controlled birefringence (ECB) effect: Birefringence

Implementation Method 2

for IPS (in-plane switching) displays or FFS (fringe field switching) displays

Methodology Applied
Scientific EffectIn-plane switching (IPS) effect:

Implementation Method 3

for IPS (in-plane switching) displays or FFS (fringe field switching) displays

Methodology Applied
Scientific EffectFringe field switching (FFS) effect:

Data Source

PatentUS11453824B2Liquid-crystalline medium
Publication Date: 2022.09.27 MERCK PATENT GMBH
  • US11453824B2 patent drawing
  • US11453824B2 patent drawing
  • US11453824B2 patent drawing

AI summary

The invention relates to a liquid-crystalline medium and to the use thereof for an active-matrix display, in particular based on the VA, PSA, PS-VA, PM-VA, SS-VA, PALC, IPS, PS-IPS, FFS or PS-FFS effect.