Liquid Crystalline Medium for VA Display Transmission

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Solution Overview

Problem

Current liquid crystal displays face challenges with low transmission values, high switching times, and insufficient specific resistance, particularly in VA applications, which affect display performance and battery life.

Innovation Solution

A liquid-crystalline medium with negative dielectric anisotropy is developed, comprising specific compounds that reduce the elastic constant K11 and increase dielectric anisotropy, optimizing transmission and switching times while maintaining high specific resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional liquid crystal mixtures are used, then the display can operate, but transmission values are low and switching times are high

Engineering Contradiction:
Improvetransmission valueVSAvoidswitching time
Core Design Contradiction:
Illumination intensityVSLoss of time

Solution Approach 1:

The patent changes the molecular structure parameters of liquid crystal compounds by introducing specific radical groups (cyclohexyl, phenyl, pyrimidine, triazine) and adjusting their ratios. This modifies key physical parameters including dielectric anisotropy (Δε), elastic constants (K11, K22, K33), and rotational viscosity (γ1), achieving optimal balance for high transmission and fast switching

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite liquid crystal mixture containing 2-25 different compounds in specific ratios. The mixture combines compounds with negative dielectric anisotropy and specific elastic constant ratios (K3/K1 ≥ 0.5) to achieve synergistic effects that improve both transmission and switching performance beyond what single compounds can provide

Inventive Principle:
Principle #40Composite materials

2Loss of time

If liquid crystal mixtures are optimized for fast switching, then switching times decrease, but specific resistance becomes insufficient

Engineering Contradiction:
Improveswitching timeVSAvoidspecific resistance
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The patent carefully adjusts molecular structure parameters including chain length, radical groups, and core structures to control rotational viscosity and specific resistance independently. By optimizing these parameters within specific ranges, the mixture achieves fast switching while maintaining high specific resistance for display stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces compounds with specific local molecular characteristics (cyclohexyl rings, aromatic groups, heterocyclic structures) that locally enhance dielectric properties and resistance. These localized structural features contribute to overall mixture performance without compromising switching speed

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If the elastic constant K11 is reduced to improve transmission, then transmission increases, but the balance with other elastic constants K3/K1 ratio may be affected

Engineering Contradiction:
ImprovetransmissionVSAvoidelastic constant ratio K3/K1
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent simultaneously optimizes multiple elastic constant parameters by selecting compounds with specific molecular structures. The mixture achieves K11 values in an optimized range while maintaining K3/K1 ≥ 0.5, balancing transmission performance with electro-optical stability for reliable display operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite mixture combines compounds with complementary elastic constant characteristics. Some compounds contribute to reducing K11 for high transmission, while others maintain the K3/K1 ratio for stability, creating a balanced overall performance that neither single compound could achieve alone

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The medium achieves improved transmission, short switching times, and stable resistance, enhancing display performance and extending battery life.

Implementation Method 1

electro-optical display elements based on the ECB effect

Methodology Applied
Scientific EffectElectro-optical effect: Electro-Optic Effects

Implementation Method 2

The principle of electrically controlled birefringence, the ECB effect (electrically controlled birefringence) or DAP effect (deformation of erected phases)

Methodology Applied
Scientific EffectElectrically controlled birefringence: Birefringence

Implementation Method 3

liquid crystalline phases must have high values for the ratio of the elastic constant K 3 /K 1 , high values for the optical anisotropy Δn and values for the dielectric anisotropy of Δε ≤ -0.5

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 4

high values for the optical anisotropy Δn

Methodology Applied
Scientific EffectOptical anisotropy: Birefringence

Data Source

PatentEP3067406B1Liquid crystalline medium
Publication Date: 2019.04.24 MERCK PATENT GMBH
  • EP3067406B1 patent drawing
  • EP3067406B1 patent drawing
  • EP3067406B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium containing at least one compound of formula IA, wherein Z1 is a single bond, -CH2CH2-, -CH=CH-, -CH2O-, -OCH2-, -CF2O-, -OCF2-, -COO-, -OCO-, -C2F4-, -C≡C-, -CF=CF-, -CH=CHCHO-, -CH2CF2O-, and additionally at least one compound of formula CC-nV and/or the compound of formula CC-V-V1, where n is 2, 3, 4, 5 or 6, with the provisos that - the percentage of the compound(s) of formula IA is greater than or equal to the percentage of CC-nV, and/or - the percentage of the compound(s) of formula IA is greater than the percentage of CC-V-V1, wherein the percentage refers to the liquid-crystalline medium, as well as its use for an active matrix display, especially based on the VA, PSA, PVA, PS-VA, SS-VA, SA-VA, PA-VA, PALC, FFS, PS-FFS, PS-IPS or IPS effect.