Liquid Detergent Composition with Stable Viscosity

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Solution Overview

Problem

High foaming liquid detergents experience significant viscosity changes with temperature, leading to unpredictable flow characteristics and dosage control issues when used in hand-washing applications.

Innovation Solution

A high foaming liquid detergent composition with a specific formulation of 5-17.5 wt.% anionic surfactants, 0-0.5 wt.% nonionic surfactants, 2-4 wt.% polyethylene glycol, and at least 50 wt.% water, which maintains stable viscosity between 10°C and 40°C, ensuring predictable flow and high foaming capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If high foaming liquid detergent is formulated, then foaming performance is improved, but viscosity stability across temperature range deteriorates

Engineering Contradiction:
Improvefoam volumeVSAvoidviscosity stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the molecular weight parameter of polyethylene glycol from conventional high values (10,000-1,000,000) to a specific low range (4,000-6,000). This parameter change fundamentally alters the temperature-viscosity relationship, enabling the detergent to maintain stable viscosity across temperature ranges while achieving high foaming performance of at least 100ml

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite surfactant system combining non-alkoxylated anionic surfactants (linear alkylbenzene sulphonate, alpha-olefin sulphonate, methyl ester sulphonate, primary alcohol sulphate) with alkoxylated anionic surfactants in a specific weight ratio (95:5 to 60:40). This composite approach synergistically achieves both high foaming capability and temperature-stable viscosity

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional high foam detergent is used, then foaming capability is improved, but dosage control precision deteriorates

Engineering Contradiction:
Improvefoam generationVSAvoiddosage control
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

By changing the molecular weight parameter of polyethylene glycol to 4,000-6,000, the patent achieves a unique viscosity profile that remains stable (5-100 cP) across the temperature range of 10-40°C. This stability enables precise dosage control in hand-washing applications while maintaining high foaming performance, as the detergent flow characteristics become predictable and controllable

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves stable viscosity and high foaming performance across a temperature range, enhancing the reliability of hand-washing applications by maintaining consistent flow characteristics and lather production.

Implementation Method 1

A high foaming liquid detergent composition whose viscosity does not change substantially within the temperature range in which the composition is normally used (10°C to 40°C)... the liquid detergent composition has stable viscosity between a temperature range of 10 and 40 °C

Methodology Applied
Scientific EffectViscosity-temperature relationship modification:

Implementation Method 2

5 to 17.5 wt.% of one or more anionic surfactants... wherein the liquid detergent composition forms a foam volume of at least 100ml... enhancing the reliability of hand-washing applications by maintaining consistent flow characteristics and lather production

Methodology Applied
Scientific EffectFoam formation: Foam

Data Source

PatentEP3630933B1Liquid detergent composition
Publication Date: 2023.10.25 UNILEVER GLOBAL IP LTD
  • EP3630933B1 patent drawing
  • EP3630933B1 patent drawing
  • EP3630933B1 patent drawing

AI summary

The present invention provides a liquid detergent composition comprising anionic surfactants, optionally one or more nonionic surfactants, polyethylene glycol, and water, and wherein the liquid detergent composition has a pH of 7.0 to 7.5, wherein the liquid detergent composition has a viscosity at 25°C and 20 s-1 in the range of 5 to 100 mPa s-1, and wherein the liquid laundry composition has stable viscosity between a temperature range of 10 and 40°C, and wherein the composition is adapted for application with a hand-held dispensing device used for washing by hand. The liquid detergent composition has a low constant viscosity throughout the temperature range of normal use and produces a stable foamy lather.