Liquid Developer Pigment Composite for Image Density and Fixing Strength

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing liquid developers for electrophotographic image forming struggle to achieve high image density and fixing strength simultaneously due to limitations in pigment dispersion, leading to compromised image quality and increased costs.

Innovation Solution

A liquid developer formulation incorporating a combination of carbon black, nigrosine, and organic pigments, such as phthalocyanine blue, carmine-based, and benzimidazolone-based pigments, dispersed in a polyester resin, which enhances pigment dispersion and maintains a balanced resin content to achieve high image density and fixing strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the content of pigment in toner particle is increased to achieve high image density, then image density is improved, but resin content is relatively decreased resulting in decreased fixing strength

Engineering Contradiction:
Improveimage densityVSAvoidfixing strength
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent uses a composite pigment system consisting of carbon black (10-25 mass%), nigrosine (3-15 mass%), and organic pigment (5-20 mass%) within the toner particle. This composite approach allows achieving high image density through synergistic pigment combination while maintaining resin content at adequate levels to ensure fixing strength, resolving the contradiction between pigment concentration and resin content.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If the content of pigment in toner particle is increased to achieve high image density, then image density is improved, but dispersion property of pigment in resin deteriorates

Engineering Contradiction:
Improveimage densityVSAvoiddispersion property
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent employs a composite pigment formulation where carbon black, nigrosine, and organic pigment work together to achieve uniform dispersion at high concentrations. The specific combination creates synergistic dispersion effects that prevent aggregation, maintaining pigment distribution stability even at elevated total pigment content (38-60 mass%), thus achieving both high image density and good dispersion property.

Inventive Principle:
Principle #40Composite materials

3Loss of substance

If the film thickness of image is decreased to reduce toner particle adhesion and achieve low cost, then cost is reduced, but image density needs to be maintained

Engineering Contradiction:
Improvetoner particle adhesionVSAvoidimage density
Core Design Contradiction:
Loss of substanceVSQuantity of substance

Solution Approach 1:

The patent changes the pigment composition parameters by incorporating nigrosine and organic pigment alongside carbon black, creating a formulation that achieves higher density per unit mass. This allows the toner particle to maintain sufficient image density even when applied at lower concentrations, reducing overall toner particle adhesion to the recording material while preserving image quality and reducing costs.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS9023571B2Liquid developer
Publication Date: 2015.05.05 KONICA MINOLTA INC
  • US9023571B2 patent drawing
  • US9023571B2 patent drawing
  • US9023571B2 patent drawing

AI summary

A liquid developer of the present invention includes a toner particle and an insulating liquid, the toner particle including a resin and a pigment, the resin including a polyester resin, the pigment including a first pigment, a second pigment, and a third pigment, the first pigment being a carbon black, 10 to 25 mass % of the first pigment being included in the toner particle, the second pigment being nigrosine, 3 to 15 mass % of the second pigment being included in the toner particle, the third pigment being at least one organic pigment selected from a group consisting of a phthalocyanine blue pigment, a phthalocyanine green pigment, a carmine-based pigment, a naphthol-based pigment, a quinacridon-based pigment, an azo-based pigment, a benzimidazolone-based pigment, and an isoindoline-based pigment, 5 to 20 mass % of the third pigment being included in the toner particle.