Liquid Ejection Head Siloxane Bonding for Ink-Durable Damping

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Solution Overview

Problem

Existing liquid ejection heads face issues with adhesive reliability between the damper film and adhesive due to deterioration when immersed in ink, leading to peeling, which affects the performance of adjacent nozzles.

Innovation Solution

The use of a siloxane bond between the organic film and adhesive, which enhances initial adhesive strength and maintains durability even when immersed in ink, utilizing materials like polyimides and epoxy resins with plasma treatment to generate functional groups for improved bonding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If ester bonds are used to bond the organic film and adhesive (as disclosed in WO 2020/045112), then initial adhesive strength is improved, but adhesive strength deteriorates over time when immersed in ink

Engineering Contradiction:
Improveinitial adhesive strengthVSAvoidadhesive strength durability in ink
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the chemical bonding parameter from ester bonds to siloxane bonds. This parameter change fundamentally alters the bond's chemical structure, providing both high initial strength and long-term durability in ink environments, as siloxane bonds resist degradation by ink components better than ester bonds

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material chemistry by combining silane coupling agents with the adhesive system. This creates a composite bonding mechanism where siloxane bonds form between the organic film and adhesive, integrating the benefits of both the organic film's damping properties and the siloxane bond's chemical stability in ink

Inventive Principle:
Principle #40Composite materials

2Reliability

If polyimides and LCP materials are used for the damper film, then ink resistance and heat resistance are improved, but adhesive adherence becomes difficult

Engineering Contradiction:
Improveink resistance and heat resistanceVSAvoidadhesive adherence
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent introduces silane coupling agents as intermediary substances between the polyimide/LCP damper film and the adhesive. These coupling agents act as chemical mediators that bond to both the organic film and adhesive, overcoming the inherent difficulty of adhering to these chemically stable materials while maintaining their ink and heat resistance

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the surface chemistry parameter of the polyimide/LCP film through plasma treatment or silane coupling agent application. This parameter change creates reactive sites on the film surface that enable strong chemical bonding with adhesives, while the bulk material properties (ink resistance, heat resistance) remain unchanged

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The siloxane bond ensures high initial adhesive strength and resistance to ink, preventing peeling and maintaining effective damping performance, suitable for inkjet recording devices.

Implementation Method 1

the organic film and the adhesive are bonded through a siloxane bond

Methodology Applied
Scientific EffectSiloxane bond: Chemical Bonding

Implementation Method 2

the film comprising the heat-resistant resin is subjected to surface treatment, such as a plasma treatment, to generate ester bonds with the resin composition and improve adherence

Methodology Applied
Scientific EffectPlasma treatment: Plasma

Data Source

PatentUS20250262856A1Liquid ejection head
Publication Date: 2025.08.21 CANON KK
  • US20250262856A1 patent drawing
  • US20250262856A1 patent drawing
  • US20250262856A1 patent drawing

AI summary

A liquid ejection head comprising an ejection port for ejecting liquid; a pressure chamber in which pressure acts on the liquid ejected from the ejection port; a flow path communicating with the pressure chamber; a substrate forming the flow path; and an organic film for constituting a part of a wall surface of the flow path and suppressing vibration of the liquid in the flow path, wherein the organic film is adhered, with an adhesive, to the substrate, and the organic film and the adhesive are bonded through a siloxane bond.