Liquid Metal Jet Printing With Laser Oxide Ablation and Heating

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Solution Overview

Problem

Liquid metal jet printing faces challenges in achieving satisfactory properties due to low surface temperatures and oxide layers, which inhibit remelting, coalescing, and metallurgical bonding, leading to unsatisfactory articles with voids and cold laps.

Innovation Solution

The implementation of a controlled heating and ablation system, such as the CHAMP system, which concurrently heats the substrate and ablates oxides using a laser to regulate interfacial temperatures and remove contaminants, ensuring proper thermo-fluidic processes during additive manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If liquid metal jet printing is performed without additional heating, then the process is simple and fast, but the surface temperature is insufficient to enable proper remelting, coalescing, and metallurgical bonding

Engineering Contradiction:
Improvesurface temperatureVSAvoidsystem complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent combines the heating function with the existing liquid metal jet printing system by integrating a heating source (such as a laser or resistive heating element) into the printing apparatus. This merging allows the system to simultaneously perform heating and printing operations, raising the surface temperature to enable proper remelting and metallurgical bonding without requiring separate offline heating processes.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies preliminary heating to the substrate or previously deposited metal layers before the liquid metal droplets are deposited. This preliminary action ensures that the surface is at the appropriate temperature for remelting and bonding when the droplets arrive, thereby enabling proper metallurgical bonding without compromising the overall process speed.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If offline secondary processes are used to treat the substrate surface, then oxide removal and heating are effective, but productivity is reduced due to additional processing steps

Engineering Contradiction:
Improvebonding qualityVSAvoidfabrication rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges the oxide removal and heating functions into the online liquid metal jet printing process. By integrating an ablation source (such as a pulsed laser) and heating source directly into the printing system, the substrate surface is treated concurrently with the deposition process, eliminating the need for separate offline secondary processes and maintaining high fabrication rates.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent maintains continuous operation by performing oxide ablation, heating, and droplet deposition in a continuous online manner. The useful actions of surface preparation and material deposition occur simultaneously without interruption, ensuring that the fabrication process maintains high productivity while achieving reliable metallurgical bonding.

Inventive Principle:
Principle #20Continuity of useful action

3Manufacturing precision

If the substrate surface is not heated, then the process is simple and fast, but voids and cold laps form due to insufficient remelting and coalescing

Engineering Contradiction:
Improvearticle qualityVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent integrates heating and ablation functions into the liquid metal jet printing system, combining multiple functions (droplet ejection, surface heating, oxide removal) into a single unified online process. This merging enables precise control of surface temperature to ensure complete remelting and coalescing of droplets, eliminating voids and cold laps while maintaining article quality.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If oxide layers are not removed, then the process remains simple, but metallurgical bonding is inhibited leading to unsatisfactory articles

Engineering Contradiction:
Improvemetallurgical bondingVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines oxide ablation with the liquid metal jet printing process by integrating an ablation source (such as a pulsed laser) into the printing system. This merging allows real-time removal of oxide layers from the substrate and previously deposited layers during the deposition process, ensuring clean surfaces for metallurgical bonding without requiring separate offline cleaning steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies preliminary ablation to remove oxide layers from the substrate surface and previously deposited metal layers before new droplets are deposited. This preliminary action ensures that the surface is free of oxides and contaminants that would inhibit metallurgical bonding, thereby improving reliability while maintaining process efficiency.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the quality of fabricated articles by improving remelting, coalescing, and bonding, reducing voids and cold laps, while maintaining productivity without the need for offline secondary processes.

Implementation Method 1

The controlled heating and ablation system is configured to heat the substrate and ablate oxides on a surface of the substrate. The output from the laser has a power of from about 40 watts (W) to about 1500 W.

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

The controlled heating and ablation system is configured to heat the substrate and ablate oxides on a surface of the substrate.

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 3

liquid metal jet printing includes utilizing a direct current pulse applied by an electromagnetic coil to expel molten metal drops toward the substrate

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Implementation Method 4

As the metal drops contact the substrate, the metal drops cool to form the article

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentEP4382229A1Additive manufacturing systems and methods for the same
Publication Date: 2024.06.12 XEROX CORP
  • EP4382229A1 patent drawingFigure 1
  • EP4382229A1 patent drawingFigure 2
  • EP4382229A1 patent drawingFigure 3

AI summary

An additive manufacturing device includes a stage configured to support a substrate. The device also includes a printhead disposed above the stage. The printhead is configured to heat a build material to a molten build material and to deposit the molten build material on the substrate in the form of droplets to fabricate an article. The device also includes a controlled heating and ablation system disposed proximal the printhead. The controlled heating and ablation system is configured to heat the substrate and ablate oxides on a surface of the substrate.